Silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine - characterization of this primary explosive
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898360" target="_blank" >RIV/00216275:25310/14:39898360 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/61389013:_____/14:00434654
Výsledek na webu
<a href="http://dx.doi.org/10.1002/prep.201300109" target="_blank" >http://dx.doi.org/10.1002/prep.201300109</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/prep.201300109" target="_blank" >10.1002/prep.201300109</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine - characterization of this primary explosive
Popis výsledku v původním jazyce
A new primary explosive - the silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine (AgDANT) - was synthesized and characterized. AgDANT was prepared with a 97% yield and characterized by IR, single crystal X-ray diffraction and DTA. The crystal density of AgDANT is 2.530 g?cm-3 and the molecule consists of a centro-symmetric dimer with a high degree of planarity. The intramolecular Ag-Ag distance is relatively low (331 pm) and can be considered as a strong argentophilic interaction. AgDANT is non-hygroscopic and its solubility in water (1.27 mg in 100 ml at 23°C) is on a similar level of solubility to that of silver azide. The sensitivity of AgDANT to impact is slightly higher than that for MF, sensitivity to friction is the same as for LA, and sensitivity to electric discharge is between that for LS and MF. Initiation efficiency of AgDANT was tested in electric detonators and compared to dextrinated lead azide (initiation efficiency of AgDANT is 40 mg for PETN secondary charge).
Název v anglickém jazyce
Silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine - characterization of this primary explosive
Popis výsledku anglicky
A new primary explosive - the silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine (AgDANT) - was synthesized and characterized. AgDANT was prepared with a 97% yield and characterized by IR, single crystal X-ray diffraction and DTA. The crystal density of AgDANT is 2.530 g?cm-3 and the molecule consists of a centro-symmetric dimer with a high degree of planarity. The intramolecular Ag-Ag distance is relatively low (331 pm) and can be considered as a strong argentophilic interaction. AgDANT is non-hygroscopic and its solubility in water (1.27 mg in 100 ml at 23°C) is on a similar level of solubility to that of silver azide. The sensitivity of AgDANT to impact is slightly higher than that for MF, sensitivity to friction is the same as for LA, and sensitivity to electric discharge is between that for LS and MF. Initiation efficiency of AgDANT was tested in electric detonators and compared to dextrinated lead azide (initiation efficiency of AgDANT is 40 mg for PETN secondary charge).
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CC - Organická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2014
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Propellants Explosives Pyrotechnics
ISSN
0721-3115
e-ISSN
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Svazek periodika
39
Číslo periodika v rámci svazku
2
Stát vydavatele periodika
DE - Spolková republika Německo
Počet stran výsledku
9
Strana od-do
251-259
Kód UT WoS článku
000334613000015
EID výsledku v databázi Scopus
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