Sensitive voltammetric method for determination of herbicide metribuzin using silver solid amalgam electrode
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F16%3A39901441" target="_blank" >RIV/00216275:25310/16:39901441 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1007/s00706-015-1555-z" target="_blank" >http://dx.doi.org/10.1007/s00706-015-1555-z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s00706-015-1555-z" target="_blank" >10.1007/s00706-015-1555-z</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Sensitive voltammetric method for determination of herbicide metribuzin using silver solid amalgam electrode
Popis výsledku v původním jazyce
New sensitive voltammetric method for determination of triazinone herbicide metribuzin (MTZ) was developed employing polished and mercury meniscus-modified silver solid amalgam electrode (p-, m-AgSAE). MTZ yielded two reduction signals on both used working electrodes in acidic and slightly acidic media and the positively situated peak [at about -650 mV vs. Ag|AgCl|KCl (sat.)] was found suitable for further analytical measurements. The highest responses were recorded in Britton-Robinson buffer of pH 2 (p-AgSAE) or 3 (m-AgSAE). Various voltammetric techniques like cyclic, linear sweep, and differential pulse voltammetry were used for examination of the voltammetric behavior of MTZ. Parameters of differential pulse voltammetry were optimized and low detection limits were reached (LODm-AgSAE = 6.0 x 10(-8) mol dm(-3) and LODp-AgSAE = 7.5 x 10(-8) mol dm(-3)). Moreover, excellent repeatability of determination and measurements as well was confirmed by low values of relative standard deviations of five repeated determinations [RSD (5) a parts per thousand currency sign 6.0 %] and of 11 repeated measurements [RSD (11) a parts per thousand currency sign 4.5 %], respectively. Finally, practical applicability of newly proposed methods was verified by the analysis of spiked tap and river water and by determination of MTZ in pesticide preparation with excellent results. All the obtained results were compared with those gained for classic mercury electrode.
Název v anglickém jazyce
Sensitive voltammetric method for determination of herbicide metribuzin using silver solid amalgam electrode
Popis výsledku anglicky
New sensitive voltammetric method for determination of triazinone herbicide metribuzin (MTZ) was developed employing polished and mercury meniscus-modified silver solid amalgam electrode (p-, m-AgSAE). MTZ yielded two reduction signals on both used working electrodes in acidic and slightly acidic media and the positively situated peak [at about -650 mV vs. Ag|AgCl|KCl (sat.)] was found suitable for further analytical measurements. The highest responses were recorded in Britton-Robinson buffer of pH 2 (p-AgSAE) or 3 (m-AgSAE). Various voltammetric techniques like cyclic, linear sweep, and differential pulse voltammetry were used for examination of the voltammetric behavior of MTZ. Parameters of differential pulse voltammetry were optimized and low detection limits were reached (LODm-AgSAE = 6.0 x 10(-8) mol dm(-3) and LODp-AgSAE = 7.5 x 10(-8) mol dm(-3)). Moreover, excellent repeatability of determination and measurements as well was confirmed by low values of relative standard deviations of five repeated determinations [RSD (5) a parts per thousand currency sign 6.0 %] and of 11 repeated measurements [RSD (11) a parts per thousand currency sign 4.5 %], respectively. Finally, practical applicability of newly proposed methods was verified by the analysis of spiked tap and river water and by determination of MTZ in pesticide preparation with excellent results. All the obtained results were compared with those gained for classic mercury electrode.
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CB - Analytická chemie, separace
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2016
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Monatshefte fur Chemie
ISSN
0026-9247
e-ISSN
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Svazek periodika
147
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
AT - Rakouská republika
Počet stran výsledku
11
Strana od-do
219-229
Kód UT WoS článku
000367521400028
EID výsledku v databázi Scopus
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