Concerning the Shock Sensitivities of Certain Plastic Bonded Explosives Based on Attractive Cyclic Nitramines

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911087" target="_blank" >RIV/00216275:25310/17:39911087 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.22211/cejem/78088" target="_blank" >http://dx.doi.org/10.22211/cejem/78088</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.22211/cejem/78088" target="_blank" >10.22211/cejem/78088</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Concerning the Shock Sensitivities of Certain Plastic Bonded Explosives Based on Attractive Cyclic Nitramines

Popis výsledku v původním jazyce

Plastic bonded explosives (PBXs) based on ε-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (ε-HNIW), 1,3,5-trinitro-1,3,5-triazinane (RDX), β-1,3,5,7-tetranitro-1,3,5,7-tetrazocane (β-HMX) and cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d]imidazole (BCHMX) were prepared using a hydroxyl-terminated polybutadiene as a binder (HTPB) and cured with hexamethylene di-isocyanate (HMDI). Recently published data for analogous PBXs with a polyisobutylene binder (i.e. a C4 matrix) are also included. All of these PBXs were tested using the Small Scale Water Gap Test according to STANAG 4490, the results of which are directly proportional to the impact and friction sensitivities of the PBXs studied. Reciprocal ratios between the shock sensitivity of these PBXs and their performance were found using the volume heat of explosion as a variable; a semi-logarithmic analogue, using a representative of the detonation pressure (product ρD2) as a variable, has shown an opposite trend for three of these PBXs. A semi-logarithmic relationship between the shock sensitivity of the PBXs and the impact sensitivity of their pure nitramine fillers has confirmed the higher shock reactivity of the C4 PBXs filled with both technical ε-HNIW and RS-ε-HNIW, while for the HTPB PBXs filled with technical grade ε-HNIW, the shock sensitivity found was as expected. The shape and size of the particles should not be a reason for the increased resistance to shock of HMX-C4.

Název v anglickém jazyce

Concerning the Shock Sensitivities of Certain Plastic Bonded Explosives Based on Attractive Cyclic Nitramines

Popis výsledku anglicky

Plastic bonded explosives (PBXs) based on ε-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (ε-HNIW), 1,3,5-trinitro-1,3,5-triazinane (RDX), β-1,3,5,7-tetranitro-1,3,5,7-tetrazocane (β-HMX) and cis-1,3,4,6-tetranitro-octahydroimidazo-[4,5-d]imidazole (BCHMX) were prepared using a hydroxyl-terminated polybutadiene as a binder (HTPB) and cured with hexamethylene di-isocyanate (HMDI). Recently published data for analogous PBXs with a polyisobutylene binder (i.e. a C4 matrix) are also included. All of these PBXs were tested using the Small Scale Water Gap Test according to STANAG 4490, the results of which are directly proportional to the impact and friction sensitivities of the PBXs studied. Reciprocal ratios between the shock sensitivity of these PBXs and their performance were found using the volume heat of explosion as a variable; a semi-logarithmic analogue, using a representative of the detonation pressure (product ρD2) as a variable, has shown an opposite trend for three of these PBXs. A semi-logarithmic relationship between the shock sensitivity of the PBXs and the impact sensitivity of their pure nitramine fillers has confirmed the higher shock reactivity of the C4 PBXs filled with both technical ε-HNIW and RS-ε-HNIW, while for the HTPB PBXs filled with technical grade ε-HNIW, the shock sensitivity found was as expected. The shape and size of the particles should not be a reason for the increased resistance to shock of HMX-C4.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

21100 - Other engineering and technologies

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Central European Journal of Energetic Materials

ISSN

1733-7178

e-ISSN

—

Svazek periodika

14

Číslo periodika v rámci svazku

4

Stát vydavatele periodika

PL - Polská republika

Počet stran výsledku

13

Strana od-do

775-787

Kód UT WoS článku

000418530100002

EID výsledku v databázi Scopus

2-s2.0-85038080613