Dimeric and different polymeric copper(II) salicylates Crystal structure and spectral properties

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911355" target="_blank" >RIV/00216275:25310/17:39911355 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.molstruc.2017.02.081" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2017.02.081</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2017.02.081" target="_blank" >10.1016/j.molstruc.2017.02.081</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Dimeric and different polymeric copper(II) salicylates Crystal structure and spectral properties

Popis výsledku v původním jazyce

The small differences in synthesis condition led to formation of four new copper(II) salicylatocomplexes - two differently polymeric [Cu(4-MeOSal)(2)(mu-H2O)(2)](n)1, [Cu(mu-3,5-Br2Sal)(2)(H2O)(2)](n)2 and two dimeric [Cu(5-MeSal)(2)(MeOH)](2)center dot 2MeOH(3) [Cu(4-MeSal)(2)(EtOH)(2)](2) 4 compounds, where 4-MeOSal = 4-methoxysalicylate, 3,5-Br2Sal = 3, 5-dibromsalicylate, 5-MeSal = 5-methylsalicylate, and 4-MeSal = 4-methoxysalicylate monoanion. Complexes were characterized by elemental analysis, UV-Vis, infrared, EPR spectra and single crystal X-ray analysis. Spectral properties are in good agreement with structural information. Intermolecular interactions are responsible for building supramolecular structure. The complexes 1 and 2 build up 2D supramolecular structures by the O-H center dot center dot center dot O hydrogen bonds formation while the complexes 3 and 4 are forming 1D supramolecular chain of paddle wheel units and coordinated solvent molecules.

Název v anglickém jazyce

Dimeric and different polymeric copper(II) salicylates Crystal structure and spectral properties

Popis výsledku anglicky

The small differences in synthesis condition led to formation of four new copper(II) salicylatocomplexes - two differently polymeric [Cu(4-MeOSal)(2)(mu-H2O)(2)](n)1, [Cu(mu-3,5-Br2Sal)(2)(H2O)(2)](n)2 and two dimeric [Cu(5-MeSal)(2)(MeOH)](2)center dot 2MeOH(3) [Cu(4-MeSal)(2)(EtOH)(2)](2) 4 compounds, where 4-MeOSal = 4-methoxysalicylate, 3,5-Br2Sal = 3, 5-dibromsalicylate, 5-MeSal = 5-methylsalicylate, and 4-MeSal = 4-methoxysalicylate monoanion. Complexes were characterized by elemental analysis, UV-Vis, infrared, EPR spectra and single crystal X-ray analysis. Spectral properties are in good agreement with structural information. Intermolecular interactions are responsible for building supramolecular structure. The complexes 1 and 2 build up 2D supramolecular structures by the O-H center dot center dot center dot O hydrogen bonds formation while the complexes 3 and 4 are forming 1D supramolecular chain of paddle wheel units and coordinated solvent molecules.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Svazek periodika

1137

Číslo periodika v rámci svazku

June

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

8

Strana od-do

706-713

Kód UT WoS článku

000398870900075

EID výsledku v databázi Scopus

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