Structure-Catalytic Activity in a Series of Push-Pull Dicyanopyrazine/Dicyanoimidazole Photoredox Catalysts

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F18%3A39912803" target="_blank" >RIV/00216275:25310/18:39912803 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68407700:21340/18:00328005

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/pdf/10.1002/slct.201800719" target="_blank" >https://onlinelibrary.wiley.com/doi/pdf/10.1002/slct.201800719</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/slct.201800719" target="_blank" >10.1002/slct.201800719</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Structure-Catalytic Activity in a Series of Push-Pull Dicyanopyrazine/Dicyanoimidazole Photoredox Catalysts

Popis výsledku v původním jazyce

A series of dicyanopyrazine and dicyanoimidazole derived push-pull molecules have been prepared and further investigated as photoredox catalysts. The fundamental properties of the catalysts were studied by DSC, X-ray analysis, absorption/emission spectra, and electrochemistry and were completed with the DFT results. The catalytic activity has been evaluated in visible light induced alpha-functionalization of amines (cross-dehydrogenative coupling and annulation reaction of tetrahydroisoquinolines). Thorough structure-property-catalytic activity relationships were elucidated. The developed series of tailored organic photoredox catalysts allows synthetic chemists to perform desired reactions under sustainable and mild conditions employing solely visible light as a source of energy.

Název v anglickém jazyce

Structure-Catalytic Activity in a Series of Push-Pull Dicyanopyrazine/Dicyanoimidazole Photoredox Catalysts

Popis výsledku anglicky

A series of dicyanopyrazine and dicyanoimidazole derived push-pull molecules have been prepared and further investigated as photoredox catalysts. The fundamental properties of the catalysts were studied by DSC, X-ray analysis, absorption/emission spectra, and electrochemistry and were completed with the DFT results. The catalytic activity has been evaluated in visible light induced alpha-functionalization of amines (cross-dehydrogenative coupling and annulation reaction of tetrahydroisoquinolines). Thorough structure-property-catalytic activity relationships were elucidated. The developed series of tailored organic photoredox catalysts allows synthetic chemists to perform desired reactions under sustainable and mild conditions employing solely visible light as a source of energy.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ChemistrySelect

ISSN

2365-6549

e-ISSN

—

Svazek periodika

3

Číslo periodika v rámci svazku

16

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

9

Strana od-do

4262-4270

Kód UT WoS článku

000431626800017

EID výsledku v databázi Scopus

2-s2.0-85046091861