A new voltammetric approach for the determination of the growth retardant paclobutrazol in the presence of difenoconazole in pesticide preparations

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F23%3A39920581" target="_blank" >RIV/00216275:25310/23:39920581 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S1572665723002205?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1572665723002205?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jelechem.2023.117360" target="_blank" >10.1016/j.jelechem.2023.117360</a>

Jazyk výsledku

angličtina

Název v původním jazyce

A new voltammetric approach for the determination of the growth retardant paclobutrazol in the presence of difenoconazole in pesticide preparations

Popis výsledku v původním jazyce

Paclobutrazol (PBZ) belongs to the group of triazole pesticides, which act as inhibitors of the synthesis of phy-tohormones and thereby regulate plant growth. In this study, the electrochemical oxidation of this pesticide was investigated for the first time. PBZ provides on a boron-doped diamond electrode (BDDE) one irreversible anodic peak over a wide pH range of the supporting electrolyte at a significantly positive potential of ca. +1950 mV (vs Ag/AgCl), which is suitable for electroanalytical purposes. Based on the LC-MS analysis of the products of electrolysis, the mechanism of the electrochemical oxidation of PBZ was also proposed. The method developed for the determination of PBZ using differential pulse voltammetry in connection with BDDE in the supporting electrolyte of 0.07 mol L-1 NaOH with 33 % of acetonitrile provided a very low limit of quantification amounted to 2.6 x 10-7 mol L-1. Under optimized conditions, the determination of the stud-ied plant growth regulator is also possible in the presence of the other insecticide difenoconazole, which is usu-ally found in commercial preparations mixed with PBZ. For natural water samples with very low concentrations of pesticides, a method of analyte pre-concentration using strong acid Amberlite (R) IRC120 H catex was developed. The proposed procedures were successfully applied for the analysis of model solutions, commercially available pesticide preparations, and spiked natural waters.

Název v anglickém jazyce

A new voltammetric approach for the determination of the growth retardant paclobutrazol in the presence of difenoconazole in pesticide preparations

Popis výsledku anglicky

Paclobutrazol (PBZ) belongs to the group of triazole pesticides, which act as inhibitors of the synthesis of phy-tohormones and thereby regulate plant growth. In this study, the electrochemical oxidation of this pesticide was investigated for the first time. PBZ provides on a boron-doped diamond electrode (BDDE) one irreversible anodic peak over a wide pH range of the supporting electrolyte at a significantly positive potential of ca. +1950 mV (vs Ag/AgCl), which is suitable for electroanalytical purposes. Based on the LC-MS analysis of the products of electrolysis, the mechanism of the electrochemical oxidation of PBZ was also proposed. The method developed for the determination of PBZ using differential pulse voltammetry in connection with BDDE in the supporting electrolyte of 0.07 mol L-1 NaOH with 33 % of acetonitrile provided a very low limit of quantification amounted to 2.6 x 10-7 mol L-1. Under optimized conditions, the determination of the stud-ied plant growth regulator is also possible in the presence of the other insecticide difenoconazole, which is usu-ally found in commercial preparations mixed with PBZ. For natural water samples with very low concentrations of pesticides, a method of analyte pre-concentration using strong acid Amberlite (R) IRC120 H catex was developed. The proposed procedures were successfully applied for the analysis of model solutions, commercially available pesticide preparations, and spiked natural waters.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

<a href="/cs/project/GA20-01589S" target="_blank" >GA20-01589S: Nové strategie pro zlepšení senzorových vlastností nových elektrodových materiálů prostřednictvím jejich předúpravy či modifikace povrchu</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Electroanalytical Chemistry

ISSN

1572-6657

e-ISSN

1873-2569

Svazek periodika

935

Číslo periodika v rámci svazku

March

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

10

Strana od-do

117360

Kód UT WoS článku

000966033100001

EID výsledku v databázi Scopus

2-s2.0-85151445055