Low Valent N-Coordinated Cations and Dications of Heavier Group 14 Elements: Lewis Acids or Bases?

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F23%3A39920648" target="_blank" >RIV/00216275:25310/23:39920648 - isvavai.cz</a>

Výsledek na webu

<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202300505" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202300505</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejic.202300505" target="_blank" >10.1002/ejic.202300505</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Low Valent N-Coordinated Cations and Dications of Heavier Group 14 Elements: Lewis Acids or Bases?

Popis výsledku v původním jazyce

Low-valent N-coordinated cations and dications of heavier group 14 elements are of great interest in recent years. Their unique electronic structure gives them an ambiphilic character, as they contain both a lone electron pair and an empty p-orbital on the central metal atom. Thanks to their nucleophilic character, these compounds can act as ligands in transition metal chemistry, and conversely, their electrophilic character allows them to interact with a wide range of organic substrates and thus replace catalysts based on transition metal complexes in many chemical transformations. The aim of this article is to summarize the synthesis of N-coordinated ionic compounds of heavier group 14 elements with their subsequent reactivity towards various nucleophiles and electrophiles.

Název v anglickém jazyce

Low Valent N-Coordinated Cations and Dications of Heavier Group 14 Elements: Lewis Acids or Bases?

Popis výsledku anglicky

Low-valent N-coordinated cations and dications of heavier group 14 elements are of great interest in recent years. Their unique electronic structure gives them an ambiphilic character, as they contain both a lone electron pair and an empty p-orbital on the central metal atom. Thanks to their nucleophilic character, these compounds can act as ligands in transition metal chemistry, and conversely, their electrophilic character allows them to interact with a wide range of organic substrates and thus replace catalysts based on transition metal complexes in many chemical transformations. The aim of this article is to summarize the synthesis of N-coordinated ionic compounds of heavier group 14 elements with their subsequent reactivity towards various nucleophiles and electrophiles.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GA23-06548S" target="_blank" >GA23-06548S: Superhydrofobní materiály na bázi heteroboroxinů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

1099-0682

Svazek periodika

26

Číslo periodika v rámci svazku

34

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

13

Strana od-do

"e202300505"

Kód UT WoS článku

001085611500001

EID výsledku v databázi Scopus

2-s2.0-85174242333