Influence of temperature on early hydration of Portland cement–metakaolin–slag system

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F16%3APU119657" target="_blank" >RIV/00216305:26310/16:PU119657 - isvavai.cz</a>

Výsledek na webu

<a href="http://link.springer.com/article/10.1007/s10973-016-5592-6" target="_blank" >http://link.springer.com/article/10.1007/s10973-016-5592-6</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10973-016-5592-6" target="_blank" >10.1007/s10973-016-5592-6</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Influence of temperature on early hydration of Portland cement–metakaolin–slag system

Popis výsledku v původním jazyce

The hydration of ternary blended cements comprising Portland cement, metakaolin and blast-furnace slag was studied at different temperatures of 30, 40, 50 and 60 °C by isothermal calorimetry. Phase composition of hydration products was determined by thermal analysis and X-ray diffraction for sample hydrated at 60 °C. Hydration involves different sequential and successive reactions in which mechanism, kinetics and products are strongly influenced by temperature. Activation energy for each exothermic reaction was determined. The linear trend of heat flow maxima for 2nd, 3rd and 4th exotherm versus temperature was revealed. The first peak is related to formation of mostly amorphous aluminate hydrates with no evidence of crystalline ettringite. Formation of first crystalline ettringite detected by X-ray diffraction was correlated with the distinct 3rd peak that occurs after 2nd “silicate” peak that corresponds to formation of calcium silicate hydrates and calcium hydroxide. The 4th peak recognizable at temperatures above 40 °C is related to the conversion of ettringite to hemicarbonate.

Název v anglickém jazyce

Influence of temperature on early hydration of Portland cement–metakaolin–slag system

Popis výsledku anglicky

The hydration of ternary blended cements comprising Portland cement, metakaolin and blast-furnace slag was studied at different temperatures of 30, 40, 50 and 60 °C by isothermal calorimetry. Phase composition of hydration products was determined by thermal analysis and X-ray diffraction for sample hydrated at 60 °C. Hydration involves different sequential and successive reactions in which mechanism, kinetics and products are strongly influenced by temperature. Activation energy for each exothermic reaction was determined. The linear trend of heat flow maxima for 2nd, 3rd and 4th exotherm versus temperature was revealed. The first peak is related to formation of mostly amorphous aluminate hydrates with no evidence of crystalline ettringite. Formation of first crystalline ettringite detected by X-ray diffraction was correlated with the distinct 3rd peak that occurs after 2nd “silicate” peak that corresponds to formation of calcium silicate hydrates and calcium hydroxide. The 4th peak recognizable at temperatures above 40 °C is related to the conversion of ettringite to hemicarbonate.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/LO1211" target="_blank" >LO1211: Centrum materiálového výzkumu na FCH VUT v Brně - udržitelnost a rozvoj</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Thermal Analysis and Calorimetry

ISSN

1388-6150

e-ISSN

1588-2926

Svazek periodika

neuveden

Číslo periodika v rámci svazku

10973

Stát vydavatele periodika

HU - Maďarsko

Počet stran výsledku

10

Strana od-do

1-10

Kód UT WoS článku

000392337000034

EID výsledku v databázi Scopus

2-s2.0-84975113068