Influence of temperature on early hydration of Portland cement–metakaolin–slag system
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F26232511%3A_____%2F17%3AN0000066" target="_blank" >RIV/26232511:_____/17:N0000066 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1007/s10973-016-5592-6" target="_blank" >http://dx.doi.org/10.1007/s10973-016-5592-6</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10973-016-5592-6" target="_blank" >10.1007/s10973-016-5592-6</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Influence of temperature on early hydration of Portland cement–metakaolin–slag system
Popis výsledku v původním jazyce
The hydration of ternary blended cements comprising Portland cement, metakaolin and blast-furnace slag was studied at different temperatures of 30, 40, 50 and 60 °C by isothermal calorimetry. Phase composition of hydration products was determined by thermal analysis and X-ray diffraction for sample hydrated at 60 °C. Hydration involves different sequential and successive reactions in which mechanism, kinetics and products are strongly influenced by temperature. Activation energy for each exothermic reaction was determined. The linear trend of heat flow maxima for 2nd, 3rd and 4th exotherm versus temperature was revealed. The first peak is related to formation of mostly amorphous aluminate hydrates with no evidence of crystalline ettringite. Formation of first crystalline ettringite detected by X-ray diffraction was correlated with the distinct 3rd peak that occurs after 2nd “silicate” peak that corresponds to formation of calcium silicate hydrates and calcium hydroxide. The 4th peak recognizable at temperatures above 40 °C is related to the conversion of ettringite to hemicarbonate.
Název v anglickém jazyce
Influence of temperature on early hydration of Portland cement–metakaolin–slag system
Popis výsledku anglicky
The hydration of ternary blended cements comprising Portland cement, metakaolin and blast-furnace slag was studied at different temperatures of 30, 40, 50 and 60 °C by isothermal calorimetry. Phase composition of hydration products was determined by thermal analysis and X-ray diffraction for sample hydrated at 60 °C. Hydration involves different sequential and successive reactions in which mechanism, kinetics and products are strongly influenced by temperature. Activation energy for each exothermic reaction was determined. The linear trend of heat flow maxima for 2nd, 3rd and 4th exotherm versus temperature was revealed. The first peak is related to formation of mostly amorphous aluminate hydrates with no evidence of crystalline ettringite. Formation of first crystalline ettringite detected by X-ray diffraction was correlated with the distinct 3rd peak that occurs after 2nd “silicate” peak that corresponds to formation of calcium silicate hydrates and calcium hydroxide. The 4th peak recognizable at temperatures above 40 °C is related to the conversion of ettringite to hemicarbonate.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20400 - Chemical engineering
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Thermal Analysis and Calorimetry
ISSN
1588-2926
e-ISSN
—
Svazek periodika
2017
Číslo periodika v rámci svazku
127
Stát vydavatele periodika
HU - Maďarsko
Počet stran výsledku
10
Strana od-do
309-318
Kód UT WoS článku
000392337000034
EID výsledku v databázi Scopus
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