Surface modification of glass fibers by oxidized plasma coatings to improve interfacial shear strength in GF/polyester composites

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F18%3APU129485" target="_blank" >RIV/00216305:26310/18:PU129485 - isvavai.cz</a>

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/pc.24573" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/pc.24573</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/pc.24573" target="_blank" >10.1002/pc.24573</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Surface modification of glass fibers by oxidized plasma coatings to improve interfacial shear strength in GF/polyester composites

Popis výsledku v původním jazyce

Plasma-polymerized films (interlayers) of tetravinylsilane in mixture with oxygen gas (oxygen fraction 0-0.71) were coated on glass fibers (GF) used as reinforcements in GF/polyester composite. Oxygen atoms of increased concentration (0-18 at.%) were partly incorporated into the plasma polymer network, forming Si-O-C/C-O-C bonding species and partly forming side polar (hydroxyl, carbonyl) groups with enhanced oxygen fraction. The amount of oxygen in plasma coatings influenced the Young’s modulus, interfacial adhesion, and surface free energy of the interlayer. To determine the interfacial shear strength, a microindentation test was implemented for individual glass fibers on a cross-section of GF/polyester composite. The interfacial shear strength for oxidized plasma coatings was up to 21% higher than that for the non-oxidized interlayer, indicating a direct chemical effect of oxygen atoms on interphase properties. The interphase shear failure was controlled by the shear strength at the interlayer/fiber interface as follows from experimental and model data.

Název v anglickém jazyce

Surface modification of glass fibers by oxidized plasma coatings to improve interfacial shear strength in GF/polyester composites

Popis výsledku anglicky

Plasma-polymerized films (interlayers) of tetravinylsilane in mixture with oxygen gas (oxygen fraction 0-0.71) were coated on glass fibers (GF) used as reinforcements in GF/polyester composite. Oxygen atoms of increased concentration (0-18 at.%) were partly incorporated into the plasma polymer network, forming Si-O-C/C-O-C bonding species and partly forming side polar (hydroxyl, carbonyl) groups with enhanced oxygen fraction. The amount of oxygen in plasma coatings influenced the Young’s modulus, interfacial adhesion, and surface free energy of the interlayer. To determine the interfacial shear strength, a microindentation test was implemented for individual glass fibers on a cross-section of GF/polyester composite. The interfacial shear strength for oxidized plasma coatings was up to 21% higher than that for the non-oxidized interlayer, indicating a direct chemical effect of oxygen atoms on interphase properties. The interphase shear failure was controlled by the shear strength at the interlayer/fiber interface as follows from experimental and model data.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20505 - Composites (including laminates, reinforced plastics, cermets, combined natural and synthetic fibre fabrics; filled composites)

Projekt

<a href="/cs/project/GA16-09161S" target="_blank" >GA16-09161S: Syntéza multifunkčních plazmových polymerů pro polymerní kompozity bez rozhraní</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Polymer Composites

ISSN

0272-8397

e-ISSN

1548-0569

Svazek periodika

neuveden

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

1-8

Kód UT WoS článku

000459570800017

EID výsledku v databázi Scopus

2-s2.0-85028862709