HYDROGENATION PROPERTIES OF BALL-MILLED Mg-Ti-C-Zr COMPOSITE

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F16%3APU143716" target="_blank" >RIV/00216305:26620/16:PU143716 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68081723:_____/16:00468223

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

HYDROGENATION PROPERTIES OF BALL-MILLED Mg-Ti-C-Zr COMPOSITE

Popis výsledku v původním jazyce

The hydrogen storage properties of ball-milled Mg-Ti-Zr-C composite (1.8 wt.% Ti, 1.9 wt.% Zr and 0.2 wt.% C) were investigated. It has been previously shown, that the addition of Ti, Zr and C improved its storage properties. This beneficial effect of additives upon hydrogen storage properties can be explained by catalysis by the particles rich in Ti or Zr located on the surface of Mg grains. They provide effective pathways for the hydrogen diffusion into the MgH2. The morphological and microstructural characteristics were investigated by scanning electron microscopy and by X-ray diffraction. The hydrogen sorption was measured by Sieverts method using Setaram PCT-Pro device. In this paper, sorption behaviour of the composite after ball-milling and after aging on the air was compared. The ball-milled composite adsorbed 3.5 wt.% H-2 within 10 min at 623 K. However, hydrogen storage capacity of the composite aged on the air for 7 months remarkably decreased: The aged composite adsorbed within 10 min only 2 wt.% H-2 at 623 K and the sorption capacity decreased from 4.7 wt.% H-2 to 2.1 wt.% H-2.

Název v anglickém jazyce

HYDROGENATION PROPERTIES OF BALL-MILLED Mg-Ti-C-Zr COMPOSITE

Popis výsledku anglicky

The hydrogen storage properties of ball-milled Mg-Ti-Zr-C composite (1.8 wt.% Ti, 1.9 wt.% Zr and 0.2 wt.% C) were investigated. It has been previously shown, that the addition of Ti, Zr and C improved its storage properties. This beneficial effect of additives upon hydrogen storage properties can be explained by catalysis by the particles rich in Ti or Zr located on the surface of Mg grains. They provide effective pathways for the hydrogen diffusion into the MgH2. The morphological and microstructural characteristics were investigated by scanning electron microscopy and by X-ray diffraction. The hydrogen sorption was measured by Sieverts method using Setaram PCT-Pro device. In this paper, sorption behaviour of the composite after ball-milling and after aging on the air was compared. The ball-milled composite adsorbed 3.5 wt.% H-2 within 10 min at 623 K. However, hydrogen storage capacity of the composite aged on the air for 7 months remarkably decreased: The aged composite adsorbed within 10 min only 2 wt.% H-2 at 623 K and the sorption capacity decreased from 4.7 wt.% H-2 to 2.1 wt.% H-2.

Druh

D - Stať ve sborníku

CEP obor

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OECD FORD obor

20506 - Coating and films

Projekt

<a href="/cs/project/ED1.1.00%2F02.0068" target="_blank" >ED1.1.00/02.0068: CEITEC - central european institute of technology</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2016

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

METAL 2016: 25TH ANNIVERSARY INTERNATIONAL CONFERENCE ON METALLURGY AND MATERIALS

ISBN

978-80-87294-67-3

ISSN

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e-ISSN

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Počet stran výsledku

5

Strana od-do

1445-1449

Název nakladatele

Neuveden

Místo vydání

neuveden

Místo konání akce

Brno

Datum konání akce

25. 5. 2016

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

000391251200236