Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU145145" target="_blank" >RIV/00216305:26620/22:PU145145 - isvavai.cz</a>

Výsledek na webu

<a href="http://www.doiserbia.nb.rs/Article.aspx?ID=0350-820X2201105P#.Yt_peHZBw2w" target="_blank" >http://www.doiserbia.nb.rs/Article.aspx?ID=0350-820X2201105P#.Yt_peHZBw2w</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.2298/SOS2201105P" target="_blank" >10.2298/SOS2201105P</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent

Popis výsledku v původním jazyce

In this study, the structure, morphology and composition of the synthesized magnetite/3D-printed wollastonite (3D_W/M) composite were characterized, and its adsorption performance with respect to As(V) and Cr(VI) were studied. Magnetite (MG) modified 3D printed wollastonite was obtained by two step procedure: modification of 3D_W with 3-aminoproylsilane (APTES) followed by controlled magnetite (MG) deposition to obtain 3D_W/M adsorbent. The structure/properties of 3D_W/M were confirmed by applying FTIR, XRD, TGD/DTA, and SEM analysis. The adsorption properties of hybrid adsorbents were carried out for As(V) and Cr(VI) removal - one relative to the initial pH value, the adsorbent mass, the temperature, and the adsorption time. Time-dependent adsorption study was best described by pseudo-second order equation, while Weber Morris analysis showed that intraparticle diffusion controled diffusional transport. Similar activation energy, 17.44 and 14.49 kJ.mol(-1) for adsorption As(V) and Cr(VI) on 3D_W/M, respectively, indicated main contribution of physical adsorption. Determination of adsorption parameters was performed by applying different adsorption isotherm models, and the best fit was obtained using Freundlich model. The adsorption capacity of 24.16 and 29.6 mg g(-1) for As(V) and Cr(VI) at 2 degrees C, Co = 5.5 and 5.3 mg L-l, respectively, were obtained. Thermodynamic study indicated favourable process at a higher temperature. Preliminary fixed-bed column study and results fitting with Bohart-Adams, Yoon-Nelson, Thomas, and Modified dose-response model showed good agreement with results from the batch study.

Název v anglickém jazyce

Removal of the As(V) and Cr(VI) from the Water Using Magnetite/3D-Printed Wollastonite Hybrid Adsorbent

Popis výsledku anglicky

In this study, the structure, morphology and composition of the synthesized magnetite/3D-printed wollastonite (3D_W/M) composite were characterized, and its adsorption performance with respect to As(V) and Cr(VI) were studied. Magnetite (MG) modified 3D printed wollastonite was obtained by two step procedure: modification of 3D_W with 3-aminoproylsilane (APTES) followed by controlled magnetite (MG) deposition to obtain 3D_W/M adsorbent. The structure/properties of 3D_W/M were confirmed by applying FTIR, XRD, TGD/DTA, and SEM analysis. The adsorption properties of hybrid adsorbents were carried out for As(V) and Cr(VI) removal - one relative to the initial pH value, the adsorbent mass, the temperature, and the adsorption time. Time-dependent adsorption study was best described by pseudo-second order equation, while Weber Morris analysis showed that intraparticle diffusion controled diffusional transport. Similar activation energy, 17.44 and 14.49 kJ.mol(-1) for adsorption As(V) and Cr(VI) on 3D_W/M, respectively, indicated main contribution of physical adsorption. Determination of adsorption parameters was performed by applying different adsorption isotherm models, and the best fit was obtained using Freundlich model. The adsorption capacity of 24.16 and 29.6 mg g(-1) for As(V) and Cr(VI) at 2 degrees C, Co = 5.5 and 5.3 mg L-l, respectively, were obtained. Thermodynamic study indicated favourable process at a higher temperature. Preliminary fixed-bed column study and results fitting with Bohart-Adams, Yoon-Nelson, Thomas, and Modified dose-response model showed good agreement with results from the batch study.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Science of Sintering

ISSN

0350-820X

e-ISSN

—

Svazek periodika

54

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

RS - Srbská republika

Počet stran výsledku

20

Strana od-do

105-124

Kód UT WoS článku

000777415500010

EID výsledku v databázi Scopus

2-s2.0-85127680223