Structural and electrical characterization of cadmium phosphate glasses doped with different concentration of sodium chloride

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F24%3APU155963" target="_blank" >RIV/00216305:26620/24:PU155963 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68081731:_____/24:00602200

Výsledek na webu

<a href="https://iopscience.iop.org/article/10.1088/1402-4896/ad8822" target="_blank" >https://iopscience.iop.org/article/10.1088/1402-4896/ad8822</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1088/1402-4896/ad8822" target="_blank" >10.1088/1402-4896/ad8822</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Structural and electrical characterization of cadmium phosphate glasses doped with different concentration of sodium chloride

Popis výsledku v původním jazyce

The electrical characteristics of cadmium phosphate glasses doped with varying concentrations of sodium chloride [ Cd-3( PO4)(2)](1-x) [ NaCl](x) , where x = 0, 2, 4 ,6 mol.% NaCl, were investigated with respect to both dopant levels and temperature. Electrical impedance spectroscopy was employed, and impedance measurements were taken across the frequency spectrum from 10(2) Hz to 10(6) Hz. Samples were characterized by scanning electron microscopy-energy dispersive x-ray spectroscopy, x-ray diffraction analysis and Fourier Transform Infrared Spectroscopy. The fi ndings revealed a decrease in bulk resistance with increasing temperature and dopant concentration, indicating a rise in DC- conductivity and suggesting a semiconducting behavior in the material. Moreover, the activation energy values were noted to decrease as dopant concentration increased. Analysis of the AC-conductivity variation with frequency delineated two distinct regions: a low-frequency region where AC-conductivity increased with frequency, indicative of a "pumping force" effect aiding charge carrier movement through various conduction states, and a high-frequency region or frequency-independent zone signifying a transition towards a more ohmic behavior in the material. The study highlighted a decrease in both the dielectric constant and dielectric loss with rising temperature and frequency across all dopant concentrations. Furthermore, the Reaction Coefficient "s" was found to be less than one, suggesting that the conduction mechanism can be elucidated in terms of the Correlated Barrier Hopping ( CBH ) model.

Název v anglickém jazyce

Structural and electrical characterization of cadmium phosphate glasses doped with different concentration of sodium chloride

Popis výsledku anglicky

The electrical characteristics of cadmium phosphate glasses doped with varying concentrations of sodium chloride [ Cd-3( PO4)(2)](1-x) [ NaCl](x) , where x = 0, 2, 4 ,6 mol.% NaCl, were investigated with respect to both dopant levels and temperature. Electrical impedance spectroscopy was employed, and impedance measurements were taken across the frequency spectrum from 10(2) Hz to 10(6) Hz. Samples were characterized by scanning electron microscopy-energy dispersive x-ray spectroscopy, x-ray diffraction analysis and Fourier Transform Infrared Spectroscopy. The fi ndings revealed a decrease in bulk resistance with increasing temperature and dopant concentration, indicating a rise in DC- conductivity and suggesting a semiconducting behavior in the material. Moreover, the activation energy values were noted to decrease as dopant concentration increased. Analysis of the AC-conductivity variation with frequency delineated two distinct regions: a low-frequency region where AC-conductivity increased with frequency, indicative of a "pumping force" effect aiding charge carrier movement through various conduction states, and a high-frequency region or frequency-independent zone signifying a transition towards a more ohmic behavior in the material. The study highlighted a decrease in both the dielectric constant and dielectric loss with rising temperature and frequency across all dopant concentrations. Furthermore, the Reaction Coefficient "s" was found to be less than one, suggesting that the conduction mechanism can be elucidated in terms of the Correlated Barrier Hopping ( CBH ) model.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10300 - Physical sciences

Projekt

<a href="/cs/project/LM2023051" target="_blank" >LM2023051: Výzkumná infrastruktura CzechNanoLab</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

PHYSICA SCRIPTA

ISSN

0031-8949

e-ISSN

1402-4896

Svazek periodika

99

Číslo periodika v rámci svazku

12

Stát vydavatele periodika

SE - Švédské království

Počet stran výsledku

14

Strana od-do

„“-„“

Kód UT WoS článku

001351324500001

EID výsledku v databázi Scopus

2-s2.0-85209565222