Organosilicon and -germanium Hydrides in Catalyst-Free Hydrometallation Reactions

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F28778758%3A_____%2F17%3AN0000012" target="_blank" >RIV/28778758:_____/17:N0000012 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216275:25310/17:39911687

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701142" target="_blank" >https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201701142</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/ejic.201700630" target="_blank" >10.1002/ejic.201700630</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Organosilicon and -germanium Hydrides in Catalyst-Free Hydrometallation Reactions

Popis výsledku v původním jazyce

Group 14 element hydrides in oxidation states +IV and +II can undergo hydroelementation reactions through addition of the E–H bonds to unsaturated bonds. The neutral group 14 element(IV) hydrides do not have suitable vacant valence orbitals and as a result are only poorly effective for the hydroelementation of unsaturated bonds without addition of any initiators; however, their low-valent analogues in oxidation state +II seem to be effective in the hydroelementation of unsaturated bonds under mild conditions. The goal of this paper is to overview examples of catalyst-free hydrosilylation and hydrogermylation reactions to highlight current knowledge about uncatalysed reactions between silicon- or germanium-(II and IV) hydrides and organic molecules containing unsaturated bonds.

Název v anglickém jazyce

Organosilicon and -germanium Hydrides in Catalyst-Free Hydrometallation Reactions

Popis výsledku anglicky

Group 14 element hydrides in oxidation states +IV and +II can undergo hydroelementation reactions through addition of the E–H bonds to unsaturated bonds. The neutral group 14 element(IV) hydrides do not have suitable vacant valence orbitals and as a result are only poorly effective for the hydroelementation of unsaturated bonds without addition of any initiators; however, their low-valent analogues in oxidation state +II seem to be effective in the hydroelementation of unsaturated bonds under mild conditions. The goal of this paper is to overview examples of catalyst-free hydrosilylation and hydrogermylation reactions to highlight current knowledge about uncatalysed reactions between silicon- or germanium-(II and IV) hydrides and organic molecules containing unsaturated bonds.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GA15-07091S" target="_blank" >GA15-07091S: Nekatalyzované Hydrosilylace Indukované N→Si Koordinací</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

European Journal of Inorganic Chemistry

ISSN

1434-1948

e-ISSN

1099-0682

Svazek periodika

2017

Číslo periodika v rámci svazku

42

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

12

Strana od-do

4887-4898

Kód UT WoS článku

000415362400001

EID výsledku v databázi Scopus

2-s2.0-85033777502