Stanovení skupin OH v huminových kyselinách s využitím methylace dimethylsíranem

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13520%2F08%3A00004394" target="_blank" >RIV/44555601:13520/08:00004394 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Determination of OH groups in humic acids using methylation with dimethylsulfate

Popis výsledku v původním jazyce

The methylation of humic acids (HA) with dimethylsulfate in acetone and methanol followed by the iodometric determination of the methoxy groups (Zeisel reaction) were applied to determine the contents of OH groups in solid samples of HA of different origins. For the coal- and peat-derived HA samples, the contents of OH groups determined after methylation in acetone ranged from 6.6 to 8.7 mmol/g, whereas the contents of OH groups determined after methylation in methanol ranged from 4.0 to 5.0 mmol/g. These differences may be related to the content of carboxylic groups in the HA molecule that were not methylated in methanol, as confirmed by a comparison with results of conventional titrimetric determinations. Observed differences were interpreted as results of different polarity of both solvents and alkalinity of the reaction mixture during the methylation. The contents of alcoholic groups as well as some other minor OH groups can be estimated using the OH group contents obtained after m

Název v anglickém jazyce

Determination of OH groups in humic acids using methylation with dimethylsulfate

Popis výsledku anglicky

The methylation of humic acids (HA) with dimethylsulfate in acetone and methanol followed by the iodometric determination of the methoxy groups (Zeisel reaction) were applied to determine the contents of OH groups in solid samples of HA of different origins. For the coal- and peat-derived HA samples, the contents of OH groups determined after methylation in acetone ranged from 6.6 to 8.7 mmol/g, whereas the contents of OH groups determined after methylation in methanol ranged from 4.0 to 5.0 mmol/g. These differences may be related to the content of carboxylic groups in the HA molecule that were not methylated in methanol, as confirmed by a comparison with results of conventional titrimetric determinations. Observed differences were interpreted as results of different polarity of both solvents and alkalinity of the reaction mixture during the methylation. The contents of alcoholic groups as well as some other minor OH groups can be estimated using the OH group contents obtained after m

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CB - Analytická chemie, separace

OECD FORD obor

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Projekt

<a href="/cs/project/1M0554" target="_blank" >1M0554: Pokročilé sanační technologie a procesy</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2008

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Talanta

ISSN

0039-9140

e-ISSN

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Svazek periodika

76

Číslo periodika v rámci svazku

4

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

4

Strana od-do

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Kód UT WoS článku

000258485700040

EID výsledku v databázi Scopus

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