Robust Aluminum and Iron Phosphinate Metal-Organic Frameworks for Efficient Removal of Bisphenol A

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13520%2F20%3A43895461" target="_blank" >RIV/44555601:13520/20:43895461 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68378271:_____/20:00524270 RIV/61388980:_____/20:00524270 RIV/00216208:11320/20:10422608

Výsledek na webu

<a href="https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.0c00201" target="_blank" >https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.0c00201</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acs.inorgchem.0c00201" target="_blank" >10.1021/acs.inorgchem.0c00201</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Robust Aluminum and Iron Phosphinate Metal-Organic Frameworks for Efficient Removal of Bisphenol A

Popis výsledku v původním jazyce

Porous metal-organic frameworks (MOFs) have excellent characteristics for the adsorptive removal of environmental pollutants. Herein, we introduce a new series of highly stable MOFs constructed using Fe3+ and Al3+ metal ions and bisphosphinate linkers. The isoreticular design leads to ICR-2, ICR-6, and ICR-7 MOFs with a honeycomb arrangement of linear pores, surface areas up to 1360 m 2 g(-1), and high solvothermal stabilities. In most cases, their sorption capacity is retained even after 24 h of reflux in water. The choice of the linkers allows for fine-tuning of the pore sizes and the chemical nature of the pores. This feature can be utilized for the optimization of host-guest interactions between molecules and the pore walls. Water pollution by various endocrine disrupting chemicals has been considered a global threat to public health. In this work, we prove that the chemical stability and hydrophobic nature of the synthesized series of MOFs result in the remarkable sorption properties of these materials for endocrine disruptor bisphenol A.

Název v anglickém jazyce

Robust Aluminum and Iron Phosphinate Metal-Organic Frameworks for Efficient Removal of Bisphenol A

Popis výsledku anglicky

Porous metal-organic frameworks (MOFs) have excellent characteristics for the adsorptive removal of environmental pollutants. Herein, we introduce a new series of highly stable MOFs constructed using Fe3+ and Al3+ metal ions and bisphosphinate linkers. The isoreticular design leads to ICR-2, ICR-6, and ICR-7 MOFs with a honeycomb arrangement of linear pores, surface areas up to 1360 m 2 g(-1), and high solvothermal stabilities. In most cases, their sorption capacity is retained even after 24 h of reflux in water. The choice of the linkers allows for fine-tuning of the pore sizes and the chemical nature of the pores. This feature can be utilized for the optimization of host-guest interactions between molecules and the pore walls. Water pollution by various endocrine disrupting chemicals has been considered a global threat to public health. In this work, we prove that the chemical stability and hydrophobic nature of the synthesized series of MOFs result in the remarkable sorption properties of these materials for endocrine disruptor bisphenol A.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Inorganic Chemistry

ISSN

0020-1669

e-ISSN

—

Svazek periodika

8

Číslo periodika v rámci svazku

59

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

8

Strana od-do

5538-5545

Kód UT WoS článku

000526885800035

EID výsledku v databázi Scopus

2-s2.0-85083238687