Tailoring oxygen vacancies in Co3O4 yolk-shell nanospheres via for boosted peroxymonosulfate activation: Single-electron transfer and high-valent Co-oxo species-dominated non-radical pathways

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F23%3A00011527" target="_blank" >RIV/46747885:24620/23:00011527 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S1385894723051355" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1385894723051355</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.cej.2023.146404" target="_blank" >10.1016/j.cej.2023.146404</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Tailoring oxygen vacancies in Co3O4 yolk-shell nanospheres via for boosted peroxymonosulfate activation: Single-electron transfer and high-valent Co-oxo species-dominated non-radical pathways

Popis výsledku v původním jazyce

As Co3O4 represents a promising material for peroxymonosulfate (PMS) activation, a yolk-shell-structured nanosphere, Co3O4-x-0.20, is developed here for maximizing its catalytic activity by governing electronic structures via tailoring oxygen vacancies (OV) of Co3O4. This OV-tailored Co3O4 enables single-electron transfer and generates high-valent cobalt-oxo species (Co(IV) = O) to achieve the fastest phenol degradation. The single-electron transfer is unraveled by an electron donation of Co atoms near OV to O2 to form O2radical dot− followed by O2 evolution after 1O2 and the charge balance maintained by an electron acquisition from phenol by the electron-deficient Co atoms. Meanwhile, the generation of Co(IV) = O by the cleavage of the Ssingle bondO bond in the Co(II)-O-SO3-OH complex accepts electrons from phenol to turn back to Co(II) and Co(III), causing phenol oxidation. These results demonstrate the pre-eminence of Co3O4-x-0.20 over the reported catalysts for phenol degradation and also offer insights into the mechanism of OV triggering electron donation and enhancing Co(IV) = O generation.

Název v anglickém jazyce

Tailoring oxygen vacancies in Co3O4 yolk-shell nanospheres via for boosted peroxymonosulfate activation: Single-electron transfer and high-valent Co-oxo species-dominated non-radical pathways

Popis výsledku anglicky

As Co3O4 represents a promising material for peroxymonosulfate (PMS) activation, a yolk-shell-structured nanosphere, Co3O4-x-0.20, is developed here for maximizing its catalytic activity by governing electronic structures via tailoring oxygen vacancies (OV) of Co3O4. This OV-tailored Co3O4 enables single-electron transfer and generates high-valent cobalt-oxo species (Co(IV) = O) to achieve the fastest phenol degradation. The single-electron transfer is unraveled by an electron donation of Co atoms near OV to O2 to form O2radical dot− followed by O2 evolution after 1O2 and the charge balance maintained by an electron acquisition from phenol by the electron-deficient Co atoms. Meanwhile, the generation of Co(IV) = O by the cleavage of the Ssingle bondO bond in the Co(II)-O-SO3-OH complex accepts electrons from phenol to turn back to Co(II) and Co(III), causing phenol oxidation. These results demonstrate the pre-eminence of Co3O4-x-0.20 over the reported catalysts for phenol degradation and also offer insights into the mechanism of OV triggering electron donation and enhancing Co(IV) = O generation.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20402 - Chemical process engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Chemical engineering journal>

ISSN

1385-8947

e-ISSN

—

Svazek periodika

476

Číslo periodika v rámci svazku

NOV 15

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

20

Strana od-do

—

Kód UT WoS článku

001096457300001

EID výsledku v databázi Scopus

2-s2.0-85174149138