High Temperature Corrosion Studies of HVOF Sprayed Coatings in Molten Sulphate Salts Environment

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F47718684%3A_____%2F19%3AN0000007" target="_blank" >RIV/47718684:_____/19:N0000007 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61389021:_____/19:00555648

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

High Temperature Corrosion Studies of HVOF Sprayed Coatings in Molten Sulphate Salts Environment

Popis výsledku v původním jazyce

The generally applied requirements on lowering of emission production in the field of power industry have led, among others, into the application of low-emission combustion process of coal fired power plants. Besides the emissions reduction, this process has led to an increase of boilers parts corrosion degradation due to the reducing atmosphere in low-emission boilers, responsible for sulphide corrosion and molten salt attack. In such environment, the protection of the exposed surfaces gains importance. Among others, the thermal spraying technology can offer a suitable way of surface corrosion protection. In the present work, the high temperature corrosion behaviour of CoCrAlYTaCSi and Cr3C2-25%NiCr High Pressure/High Velocity Oxygen Fuel (HP/HVOF) sprayed coatings is evaluated and compared to the behaviour of bare structural steel (SPT360) substrate. The specimens were exposed to a molten salt environment, i. e., 12% Na2SO4 82% Fe2 (SO4)3 at 690 °C under cyclic condition, simulating the working environment in low-emission boilers of coal-fired power plants. The thermogravimetric method was used to establish the kinetics of corrosion. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) techniques were used to analyse the corrosion products and determine the corrosion mechanism. The thermogravimetric measurement shows high oxidation rate of SPT360 steel. Cr3C2-25%NiCr coating provides slightly better performance compared to CoCrAlYTaCSi coating. Based on the obtained results, both coatings were found to have higher corrosion resistance than the SPT360 steel substrate, offering a sufficient surface protection in a given environment.

Název v anglickém jazyce

High Temperature Corrosion Studies of HVOF Sprayed Coatings in Molten Sulphate Salts Environment

Popis výsledku anglicky

The generally applied requirements on lowering of emission production in the field of power industry have led, among others, into the application of low-emission combustion process of coal fired power plants. Besides the emissions reduction, this process has led to an increase of boilers parts corrosion degradation due to the reducing atmosphere in low-emission boilers, responsible for sulphide corrosion and molten salt attack. In such environment, the protection of the exposed surfaces gains importance. Among others, the thermal spraying technology can offer a suitable way of surface corrosion protection. In the present work, the high temperature corrosion behaviour of CoCrAlYTaCSi and Cr3C2-25%NiCr High Pressure/High Velocity Oxygen Fuel (HP/HVOF) sprayed coatings is evaluated and compared to the behaviour of bare structural steel (SPT360) substrate. The specimens were exposed to a molten salt environment, i. e., 12% Na2SO4 82% Fe2 (SO4)3 at 690 °C under cyclic condition, simulating the working environment in low-emission boilers of coal-fired power plants. The thermogravimetric method was used to establish the kinetics of corrosion. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) techniques were used to analyse the corrosion products and determine the corrosion mechanism. The thermogravimetric measurement shows high oxidation rate of SPT360 steel. Cr3C2-25%NiCr coating provides slightly better performance compared to CoCrAlYTaCSi coating. Based on the obtained results, both coatings were found to have higher corrosion resistance than the SPT360 steel substrate, offering a sufficient surface protection in a given environment.

Druh

D - Stať ve sborníku

CEP obor

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OECD FORD obor

20506 - Coating and films

Projekt

<a href="/cs/project/TE01020068" target="_blank" >TE01020068: Centrum výzkumu a experimentálního vývoje spolehlivé energetiky</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

METAL 2019 - 28th International Conference on Metallurgy and Materials

ISBN

978-808729492-5

ISSN

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e-ISSN

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Počet stran výsledku

7

Strana od-do

1079-1085

Název nakladatele

Tanger s.r.o.

Místo vydání

Ostrava

Místo konání akce

Hotel Voronez I; Brno; Czech Republic

Datum konání akce

22. 5. 2019

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

000539487400177