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High temperature corrosion studies of HVOF sprayed coatings in molten sulphate salts environment

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389021%3A_____%2F19%3A00555648" target="_blank" >RIV/61389021:_____/19:00555648 - isvavai.cz</a>

  • Nalezeny alternativní kódy

    RIV/47718684:_____/19:N0000007

  • Výsledek na webu

    <a href="https://www.confer.cz/metal/2019/read/885-high-temperature-corrosion-studies-of-hvof-sprayed-coatings-in-molten-sulphate-salts-environment.pdf" target="_blank" >https://www.confer.cz/metal/2019/read/885-high-temperature-corrosion-studies-of-hvof-sprayed-coatings-in-molten-sulphate-salts-environment.pdf</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.37904/metal.2019.885" target="_blank" >10.37904/metal.2019.885</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    High temperature corrosion studies of HVOF sprayed coatings in molten sulphate salts environment

  • Popis výsledku v původním jazyce

    The generally applied requirements on lowering of emission production in the field of power industry have led, among others, into the application of low-emission combustion process of coal fired power plants. Besides the emissions reduction, this process has led to an increase of boilers parts corrosion degradation due to the reducing atmosphere in low-emission boilers, responsible for sulphide corrosion and molten salt attack. In such environment, the protection of the exposed surfaces gains importance. Among others, the thermal spraying technology can offer a suitable way of surface corrosion protection. In the present work, the high temperature corrosion behaviour of CoCrAlYTaCSi and Cr3C2-25%NiCr High Pressure/High Velocity Oxygen Fuel (HP/HVOF) sprayed coatings is evaluated and compared to the behaviour of bare structural steel (SPT360) substrate. The specimens were exposed to a molten salt environment, i. e., 12% Na2SO4 + 82% Fe2(SO4)3 at 690 °C under cyclic condition, simulating the working environment in low-emission boilers of coal-fired power plants. The thermogravimetric method was used to establish the kinetics of corrosion. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) techniques were used to analyse the corrosion products and determine the corrosion mechanism. The thermogravimetric measurement shows high oxidation rate of SPT360 steel. Cr3C2-25%NiCr coating provides slightly better performance compared to CoCrAlYTaCSi coating. Based on the obtained results, both coatings were found to have higher corrosion resistance than the SPT360 steel substrate, offering a sufficient surface protection in a given environment.

  • Název v anglickém jazyce

    High temperature corrosion studies of HVOF sprayed coatings in molten sulphate salts environment

  • Popis výsledku anglicky

    The generally applied requirements on lowering of emission production in the field of power industry have led, among others, into the application of low-emission combustion process of coal fired power plants. Besides the emissions reduction, this process has led to an increase of boilers parts corrosion degradation due to the reducing atmosphere in low-emission boilers, responsible for sulphide corrosion and molten salt attack. In such environment, the protection of the exposed surfaces gains importance. Among others, the thermal spraying technology can offer a suitable way of surface corrosion protection. In the present work, the high temperature corrosion behaviour of CoCrAlYTaCSi and Cr3C2-25%NiCr High Pressure/High Velocity Oxygen Fuel (HP/HVOF) sprayed coatings is evaluated and compared to the behaviour of bare structural steel (SPT360) substrate. The specimens were exposed to a molten salt environment, i. e., 12% Na2SO4 + 82% Fe2(SO4)3 at 690 °C under cyclic condition, simulating the working environment in low-emission boilers of coal-fired power plants. The thermogravimetric method was used to establish the kinetics of corrosion. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) techniques were used to analyse the corrosion products and determine the corrosion mechanism. The thermogravimetric measurement shows high oxidation rate of SPT360 steel. Cr3C2-25%NiCr coating provides slightly better performance compared to CoCrAlYTaCSi coating. Based on the obtained results, both coatings were found to have higher corrosion resistance than the SPT360 steel substrate, offering a sufficient surface protection in a given environment.

Klasifikace

  • Druh

    D - Stať ve sborníku

  • CEP obor

  • OECD FORD obor

    20501 - Materials engineering

Návaznosti výsledku

  • Projekt

  • Návaznosti

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Ostatní

  • Rok uplatnění

    2019

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název statě ve sborníku

    METAL 2019 - 28th International Conference on Metallurgy and Materials, Conference Proceedings

  • ISBN

    978-80-87294-92-5

  • ISSN

  • e-ISSN

  • Počet stran výsledku

    7

  • Strana od-do

    (2019)

  • Název nakladatele

    TANGER Ltd.

  • Místo vydání

    Ostrava

  • Místo konání akce

    Brno

  • Datum konání akce

    22. 5. 2019

  • Typ akce podle státní příslušnosti

    WRD - Celosvětová akce

  • Kód UT WoS článku

    000539487400177