Mechanisms of electrochemical nitrogen gas reduction to ammonia under ambient conditions: a focused review
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23640%2F22%3A43970453" target="_blank" >RIV/49777513:23640/22:43970453 - isvavai.cz</a>
Výsledek na webu
<a href="https://doi.org/10.1007/s10008-022-05228-5" target="_blank" >https://doi.org/10.1007/s10008-022-05228-5</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10008-022-05228-5" target="_blank" >10.1007/s10008-022-05228-5</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Mechanisms of electrochemical nitrogen gas reduction to ammonia under ambient conditions: a focused review
Popis výsledku v původním jazyce
Electrocatalytic nitrogen reduction reaction (E-NRR) to ammonia is becoming a major topic of interest in the field of large-scale energy storage from renewable sources and water. This approach is considered as an alternative route of ammonia production that could replace the high energy demanding and polluting Haber-Bosch process or high pressure stored hydrogen from electrolysis. This focused review covers different recent aspects of ammonia production via E-NRR electrocatalysis, including the challenges of E-NRR, reaction mechanisms, different materials of E-NRR catalysts such as noble metal-based, non-noble transition metal-based oxides, nitrides, carbides, and hetero-atom-based catalysts, emphasizing bifunctional catalysts reacting at ambient pressures and temperatures, which were not included in previous reviews. In addition, we discuss important issues concerning the commonly used experimental setup, testing protocols, and various NH3 quantification methods. The various fundamental and applied research methodologies summarized in this review can serve to promote efficient research on electrocatalytic nitrogen reduction and ammonia production, making it a promising future energy storage as a synthetic alternative fuel.
Název v anglickém jazyce
Mechanisms of electrochemical nitrogen gas reduction to ammonia under ambient conditions: a focused review
Popis výsledku anglicky
Electrocatalytic nitrogen reduction reaction (E-NRR) to ammonia is becoming a major topic of interest in the field of large-scale energy storage from renewable sources and water. This approach is considered as an alternative route of ammonia production that could replace the high energy demanding and polluting Haber-Bosch process or high pressure stored hydrogen from electrolysis. This focused review covers different recent aspects of ammonia production via E-NRR electrocatalysis, including the challenges of E-NRR, reaction mechanisms, different materials of E-NRR catalysts such as noble metal-based, non-noble transition metal-based oxides, nitrides, carbides, and hetero-atom-based catalysts, emphasizing bifunctional catalysts reacting at ambient pressures and temperatures, which were not included in previous reviews. In addition, we discuss important issues concerning the commonly used experimental setup, testing protocols, and various NH3 quantification methods. The various fundamental and applied research methodologies summarized in this review can serve to promote efficient research on electrocatalytic nitrogen reduction and ammonia production, making it a promising future energy storage as a synthetic alternative fuel.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2022
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
ISSN
1432-8488
e-ISSN
1433-0768
Svazek periodika
26
Číslo periodika v rámci svazku
9
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
21
Strana od-do
1897-1917
Kód UT WoS článku
000817846800001
EID výsledku v databázi Scopus
2-s2.0-85132964634