Performance comparison of three passive samplers for monitoring of polar organic contaminants in treated municipal wastewater

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60076658%3A12520%2F24%3A43908048" target="_blank" >RIV/60076658:12520/24:43908048 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216224:14310/24:00135706

Výsledek na webu

<a href="https://doi.org/10.1016/j.scitotenv.2023.168153" target="_blank" >https://doi.org/10.1016/j.scitotenv.2023.168153</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.scitotenv.2023.168153" target="_blank" >10.1016/j.scitotenv.2023.168153</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Performance comparison of three passive samplers for monitoring of polar organic contaminants in treated municipal wastewater

Popis výsledku v původním jazyce

Over the past decades, several types of passive samplers have been developed and used to monitor polar organic compounds in aquatic environments. These samplers use different sorbents and barriers to control the uptake into the sampler, but their performance comparison is usually not well investigated. This study aimed to directly compare the performance of three samplers, i.e., the Polar Organic Chemical Integrative Sampler (POCIS), the Hydrogel-based Passive Sampler (HPS, an upscaled version of o-DGT), and the Speedisk, on a diverse suite of pharmaceuticals, per- and polyfluoroalkylated substances (PFAS), and pesticides and their metabolites. The samplers were deployed side-by-side in the treated effluent of a municipal wastewater treatment plant for different exposure times. All samplers accumulated a comparable number of compounds, and integrative uptake was observed for most compounds detected up to 28 days for POCIS, up to 14 days for HPS, and up to 42 days for Speedisk. In the integrative uptake phase, consistent surface-specific uptake was observed with a significant correlation between samplers (r &gt;= 0.76) despite differences in sampler construction, diffusion barrier, and sorbent material used. The low sampling rates compared to the literature and the low estimated overall mass transfer coefficient suggests that the water boundary layer was the main barrier controlling the uptake for all samplers. Although all devices provided comparable performance, Speedisk overcomes POCIS and HPS in several criteria, including time-integrative sampling over a long period and physical durability.

Název v anglickém jazyce

Performance comparison of three passive samplers for monitoring of polar organic contaminants in treated municipal wastewater

Popis výsledku anglicky

Over the past decades, several types of passive samplers have been developed and used to monitor polar organic compounds in aquatic environments. These samplers use different sorbents and barriers to control the uptake into the sampler, but their performance comparison is usually not well investigated. This study aimed to directly compare the performance of three samplers, i.e., the Polar Organic Chemical Integrative Sampler (POCIS), the Hydrogel-based Passive Sampler (HPS, an upscaled version of o-DGT), and the Speedisk, on a diverse suite of pharmaceuticals, per- and polyfluoroalkylated substances (PFAS), and pesticides and their metabolites. The samplers were deployed side-by-side in the treated effluent of a municipal wastewater treatment plant for different exposure times. All samplers accumulated a comparable number of compounds, and integrative uptake was observed for most compounds detected up to 28 days for POCIS, up to 14 days for HPS, and up to 42 days for Speedisk. In the integrative uptake phase, consistent surface-specific uptake was observed with a significant correlation between samplers (r &gt;= 0.76) despite differences in sampler construction, diffusion barrier, and sorbent material used. The low sampling rates compared to the literature and the low estimated overall mass transfer coefficient suggests that the water boundary layer was the main barrier controlling the uptake for all samplers. Although all devices provided comparable performance, Speedisk overcomes POCIS and HPS in several criteria, including time-integrative sampling over a long period and physical durability.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10511 - Environmental sciences (social aspects to be 5.7)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Science of the Total Environment

ISSN

0048-9697

e-ISSN

1879-1026

Svazek periodika

908

Číslo periodika v rámci svazku

neuvedeno

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

12

Strana od-do

—

Kód UT WoS článku

001109901500001

EID výsledku v databázi Scopus

2-s2.0-85175802400