Variability in the levels of fungicide residues in final beer as they are influenced by various sequences of agrochemicals used for treatment on hops

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60193697%3A_____%2F23%3AN0000017" target="_blank" >RIV/60193697:_____/23:N0000017 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.tandfonline.com/doi/full/10.1080/19440049.2023.2202773?scroll=top&needAccess=true" target="_blank" >https://www.tandfonline.com/doi/full/10.1080/19440049.2023.2202773?scroll=top&needAccess=true</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/19440049.2023.2202773" target="_blank" >10.1080/19440049.2023.2202773</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Variability in the levels of fungicide residues in final beer as they are influenced by various sequences of agrochemicals used for treatment on hops

Popis výsledku v původním jazyce

The fate of during brewing of pesticides (organic compounds and copper) from hops was determined to reveal linkages between various pesticide sequences applied in hop yards and the level of pesticides in beer. For this purpose, laboratory-scale brewing trials were carried out with conventional hops from four localities in which pest control spray programs varied. Pesticide residue analysis in samples of hopped wort, young beer, and beer was carried out by liquid chromatography in tandem with mass spectrometry (LC-MS/MS). Cu concentrations were determined using inductively coupled plasma mass spectrometry (ICP-MS). The transfer rates (%) of individual pesticides were calculated to demonstrate their ability to be transferred from hops to the brewed solutions. The pesticides exhibited different transfer rates correlating well with their log p values; however, the obtained transfer data were not related to their concentration in hops. The average transfer rates calculated for ametoctradin (15% ± 5%), mandipropamid (38% ± 4%), boscalid (48% ± 5%), and azoxystrobin (47% ± 2%) increased in good correlation with their descending log P values. On the contrary, the transfer rates of copper residues were related to residual concentrations of copper in hops and exhibited logarithmic dependency. The carryover of the sum of all pesticides in the four samples ranged from 36% to 49%, averaging 42% ± 6%. The data showed no substantial influence of various pesticide spray sequences on the percentages of overall pesticide residues carried over into beer.

Název v anglickém jazyce

Variability in the levels of fungicide residues in final beer as they are influenced by various sequences of agrochemicals used for treatment on hops

Popis výsledku anglicky

The fate of during brewing of pesticides (organic compounds and copper) from hops was determined to reveal linkages between various pesticide sequences applied in hop yards and the level of pesticides in beer. For this purpose, laboratory-scale brewing trials were carried out with conventional hops from four localities in which pest control spray programs varied. Pesticide residue analysis in samples of hopped wort, young beer, and beer was carried out by liquid chromatography in tandem with mass spectrometry (LC-MS/MS). Cu concentrations were determined using inductively coupled plasma mass spectrometry (ICP-MS). The transfer rates (%) of individual pesticides were calculated to demonstrate their ability to be transferred from hops to the brewed solutions. The pesticides exhibited different transfer rates correlating well with their log p values; however, the obtained transfer data were not related to their concentration in hops. The average transfer rates calculated for ametoctradin (15% ± 5%), mandipropamid (38% ± 4%), boscalid (48% ± 5%), and azoxystrobin (47% ± 2%) increased in good correlation with their descending log P values. On the contrary, the transfer rates of copper residues were related to residual concentrations of copper in hops and exhibited logarithmic dependency. The carryover of the sum of all pesticides in the four samples ranged from 36% to 49%, averaging 42% ± 6%. The data showed no substantial influence of various pesticide spray sequences on the percentages of overall pesticide residues carried over into beer.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Food Additives And Contaminants Part A-Chemistry Analysis Control Exposure & Risk Assessment

ISSN

1944-0049

e-ISSN

1944-0057

Svazek periodika

40

Číslo periodika v rámci svazku

5

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

12

Strana od-do

655-666

Kód UT WoS článku

000975142900001

EID výsledku v databázi Scopus

2-s2.0-85153612897