ENANTIOSELECTIVE HYDROGENATION OF C=N DOUBLE BOND BY Ru-TsDPEN CATALYST - SPECTRAL AND DFT INVESTIGATION OF THE MECHANISM

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F10%3A00023637" target="_blank" >RIV/60461373:22310/10:00023637 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

ENANTIOSELECTIVE HYDROGENATION OF C=N DOUBLE BOND BY Ru-TsDPEN CATALYST - SPECTRAL AND DFT INVESTIGATION OF THE MECHANISM

Popis výsledku v původním jazyce

Chiral compounds are of key importance for a broad range of life sciences and ne chemical products, particularly for pharmaceuticals and agrochemicals. Catalytic enantioselective synthesis is one of the most important synthetic methods for the manufacturing of chiral compounds. Among these methods catalytic asymmetric hydrogenation plays outstanding role both on laboratory and industrially scale. Nowadays asymmetric hydrogenation of C=N has an important role from the practical point of view. For its hydrogenation are reported two different methods using gaseous hydrogen or phase transfer hydrogenation. The transfer hydrogenation is from the practical point of view very useful method which uses organic sources of hydrogen, e.g. propane-2-ol, formic acid. In 1995, Noyori and coworkers published a paper [1], reporting the TsDPEN-coordinated (TsDPEN = N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) Ru(II) complex (Ru-TsDPEN) to be an excellent catalyst for the asymmetric reduction of ar

Název v anglickém jazyce

ENANTIOSELECTIVE HYDROGENATION OF C=N DOUBLE BOND BY Ru-TsDPEN CATALYST - SPECTRAL AND DFT INVESTIGATION OF THE MECHANISM

Popis výsledku anglicky

Chiral compounds are of key importance for a broad range of life sciences and ne chemical products, particularly for pharmaceuticals and agrochemicals. Catalytic enantioselective synthesis is one of the most important synthetic methods for the manufacturing of chiral compounds. Among these methods catalytic asymmetric hydrogenation plays outstanding role both on laboratory and industrially scale. Nowadays asymmetric hydrogenation of C=N has an important role from the practical point of view. For its hydrogenation are reported two different methods using gaseous hydrogen or phase transfer hydrogenation. The transfer hydrogenation is from the practical point of view very useful method which uses organic sources of hydrogen, e.g. propane-2-ol, formic acid. In 1995, Noyori and coworkers published a paper [1], reporting the TsDPEN-coordinated (TsDPEN = N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) Ru(II) complex (Ru-TsDPEN) to be an excellent catalyst for the asymmetric reduction of ar

Druh

D - Stať ve sborníku

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA104%2F09%2F1497" target="_blank" >GA104/09/1497: Studium moderních aspektů asymetrické hydrogenace iminů</a><br>

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

2010 AIChE Annual Meeting Conference Proceedings

ISBN

978-0-8169-1065-6

ISSN

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e-ISSN

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Počet stran výsledku

6

Strana od-do

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Název nakladatele

American Institute of Chemical Engineers

Místo vydání

Nashville

Místo konání akce

Salt Lake City, UT, USA

Datum konání akce

1. 1. 2010

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

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