Sorption of single enantiomers and racemic mixture of ( +/MINUS SIGN )-?-pinene into Nafion membranes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F15%3A43899353" target="_blank" >RIV/60461373:22310/15:43899353 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22340/15:43899353

Výsledek na webu

<a href="http://www.tandfonline.com/doi/full/10.1080/19443994.2014.939496" target="_blank" >http://www.tandfonline.com/doi/full/10.1080/19443994.2014.939496</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/19443994.2014.939496" target="_blank" >10.1080/19443994.2014.939496</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Sorption of single enantiomers and racemic mixture of ( +/MINUS SIGN )-?-pinene into Nafion membranes

Popis výsledku v původním jazyce

The aim of this work was to elucidate the sorption of ?-pinene in the membranes of solution-cast and melt-extruded Nafion. The extruded membrane was Nafion(R) 115 in H+ form (DuPont). The cast Nafion membrane was prepared by casting from a 20 wt.% solution of Nafion(R) (H+ form) in lower aliphatic alcohols and water. (+)-?-pinene, (MINUS SIGN )-?-pinene and racemic mixture sorption isotherms were determined by a gravimetric method using the sorption balance. It was found that the sorption of ?-pinene inthe Nafion membrane is a stereoselective process. The sorption of ?-pinene in cast Nafion is much higher than in extruded Nafion. The sorption of (+)-?-pinene in the extruded Nafion membrane is quite low while the sorption of (MINUS SIGN )-?-pinene approaches zero. The sorption of (MINUS SIGN )-?-pinene in the cast Nafion membrane is high while the sorption of (+)-?-pinene is low.

Název v anglickém jazyce

Sorption of single enantiomers and racemic mixture of ( +/MINUS SIGN )-?-pinene into Nafion membranes

Popis výsledku anglicky

The aim of this work was to elucidate the sorption of ?-pinene in the membranes of solution-cast and melt-extruded Nafion. The extruded membrane was Nafion(R) 115 in H+ form (DuPont). The cast Nafion membrane was prepared by casting from a 20 wt.% solution of Nafion(R) (H+ form) in lower aliphatic alcohols and water. (+)-?-pinene, (MINUS SIGN )-?-pinene and racemic mixture sorption isotherms were determined by a gravimetric method using the sorption balance. It was found that the sorption of ?-pinene inthe Nafion membrane is a stereoselective process. The sorption of ?-pinene in cast Nafion is much higher than in extruded Nafion. The sorption of (+)-?-pinene in the extruded Nafion membrane is quite low while the sorption of (MINUS SIGN )-?-pinene approaches zero. The sorption of (MINUS SIGN )-?-pinene in the cast Nafion membrane is high while the sorption of (+)-?-pinene is low.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GAP106%2F12%2F0569" target="_blank" >GAP106/12/0569: Membránové separace - efektivnější separace čistých enantiomerů z racemických směsí</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Desalination and Water Treatment

ISSN

1944-3994

e-ISSN

—

Svazek periodika

55

Číslo periodika v rámci svazku

11

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

6

Strana od-do

2967-2972

Kód UT WoS článku

000360216100011

EID výsledku v databázi Scopus

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