Optimization of synthesis of the nickel-cobalt oxide based anode electrocatalyst and of the related membrane-electrode assembly for alkaline water electrolysis

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F17%3A43913635" target="_blank" >RIV/60461373:22310/17:43913635 - isvavai.cz</a>

Výsledek na webu

<a href="https://ac.els-cdn.com/S0378775317302318/1-s2.0-S0378775317302318-main.pdf?_tid=80a2fba0-0114-11e8-ab5f-00000aab0f6c&acdnat=1516805000_9c6f3cabe115bb43dbc7626815e0e52b" target="_blank" >https://ac.els-cdn.com/S0378775317302318/1-s2.0-S0378775317302318-main.pdf?_tid=80a2fba0-0114-11e8-ab5f-00000aab0f6c&acdnat=1516805000_9c6f3cabe115bb43dbc7626815e0e52b</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jpowsour.2017.02.057" target="_blank" >10.1016/j.jpowsour.2017.02.057</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Optimization of synthesis of the nickel-cobalt oxide based anode electrocatalyst and of the related membrane-electrode assembly for alkaline water electrolysis

Popis výsledku v původním jazyce

In this work, the Ni-Co spinel oxides are synthesized via different methods and using different calcination temperatures. Properties of the prepared materials are compared. The best route is selected and used to prepare a Ni1+xCo2-xO4 (-1 &lt;= x &lt;= 1) series of materials in order to investigate their catalytic activity towards the oxygen evolution reaction (OER). The results show that hydroxide preparation yields NiCo2O4 oxide with the highest activity. 325 degrees C is identified as the optimum calcination temperature. Subsequently, the catalysts are tested in an electrolysis cell. To prepare an anode catalyst layer based on NiCo2O4 catalyst on top of a nickel foam substrate for membrane electrode assembly (MEA) construction, following polymer binders are used: anion-selective quaternized polyphenylene oxide (qPPO), inert polytetrafluoroethylene (PTFE (R)), and cation-selective Nafion (R). qPPO ionomer containing MEA exhibited highest OER activity. The current density obtained using a MEA containing qPPO binder attains a value of 135 mA cm(-2) at a cell voltage of 1.85 V. After 7 h chronopotentiometric experiment at a constant current density of 225 mA cm 2, the MEA employing PTFE (R) binder shows higher stability than the other binders in alkaline water electrolysis at 50 degrees C. Under similar conditions, stability of the PTFE (R)-binding MEA is examined for 135 h. Crown

Název v anglickém jazyce

Optimization of synthesis of the nickel-cobalt oxide based anode electrocatalyst and of the related membrane-electrode assembly for alkaline water electrolysis

Popis výsledku anglicky

In this work, the Ni-Co spinel oxides are synthesized via different methods and using different calcination temperatures. Properties of the prepared materials are compared. The best route is selected and used to prepare a Ni1+xCo2-xO4 (-1 &lt;= x &lt;= 1) series of materials in order to investigate their catalytic activity towards the oxygen evolution reaction (OER). The results show that hydroxide preparation yields NiCo2O4 oxide with the highest activity. 325 degrees C is identified as the optimum calcination temperature. Subsequently, the catalysts are tested in an electrolysis cell. To prepare an anode catalyst layer based on NiCo2O4 catalyst on top of a nickel foam substrate for membrane electrode assembly (MEA) construction, following polymer binders are used: anion-selective quaternized polyphenylene oxide (qPPO), inert polytetrafluoroethylene (PTFE (R)), and cation-selective Nafion (R). qPPO ionomer containing MEA exhibited highest OER activity. The current density obtained using a MEA containing qPPO binder attains a value of 135 mA cm(-2) at a cell voltage of 1.85 V. After 7 h chronopotentiometric experiment at a constant current density of 225 mA cm 2, the MEA employing PTFE (R) binder shows higher stability than the other binders in alkaline water electrolysis at 50 degrees C. Under similar conditions, stability of the PTFE (R)-binding MEA is examined for 135 h. Crown

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Power Sources

ISSN

0378-7753

e-ISSN

—

Svazek periodika

347

Číslo periodika v rámci svazku

April

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

12

Strana od-do

247-258

Kód UT WoS článku

000396955100026

EID výsledku v databázi Scopus

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