Plasmon Catalysis on Bimetallic Surface-Selective Hydrogenation of Alkynes to Alkanes or Alkenes

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43916447" target="_blank" >RIV/60461373:22310/18:43916447 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/67985858:_____/18:00507031

Výsledek na webu

<a href="https://pubs.acs.org/doi/10.1021/acs.jpcc.8b07398" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.jpcc.8b07398</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acs.jpcc.8b07398" target="_blank" >10.1021/acs.jpcc.8b07398</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Plasmon Catalysis on Bimetallic Surface-Selective Hydrogenation of Alkynes to Alkanes or Alkenes

Popis výsledku v původním jazyce

Utilization of plasmonics as a driving tool for chemical transformation triggering enables to achieve unprecedented results regarding photochemical conversion efficiency and chemical selectivity regulation. In this study, the bimetallic surface plasmon-polariton-supported grating is proposed as an effective background for plasmon-induced hydrogenation of alkynyl groups of absolute chemoselectivity. The periodical bimetallic structure consists of spatially modulated gold layers, covered with the nanometer-thick platinum layer. The alkyne bonds are covalently attached to the surface of the catalytic system through covalent grafting of the bimetallic surface with 4-ethynylbenzenediazonium tosylate, with triple bonds separated from the platinum layer by the benzene rings. The proposed bimetallic structure enables selective hydrogenation of alkyne bonds to alkenyl or alkyl moieties using cyclohexene as a hydrogen source. The selectivity of hydrogenation can be controlled by changing the structure parameters, for example, the thickness of the upper platinum layer.

Název v anglickém jazyce

Plasmon Catalysis on Bimetallic Surface-Selective Hydrogenation of Alkynes to Alkanes or Alkenes

Popis výsledku anglicky

Utilization of plasmonics as a driving tool for chemical transformation triggering enables to achieve unprecedented results regarding photochemical conversion efficiency and chemical selectivity regulation. In this study, the bimetallic surface plasmon-polariton-supported grating is proposed as an effective background for plasmon-induced hydrogenation of alkynyl groups of absolute chemoselectivity. The periodical bimetallic structure consists of spatially modulated gold layers, covered with the nanometer-thick platinum layer. The alkyne bonds are covalently attached to the surface of the catalytic system through covalent grafting of the bimetallic surface with 4-ethynylbenzenediazonium tosylate, with triple bonds separated from the platinum layer by the benzene rings. The proposed bimetallic structure enables selective hydrogenation of alkyne bonds to alkenyl or alkyl moieties using cyclohexene as a hydrogen source. The selectivity of hydrogenation can be controlled by changing the structure parameters, for example, the thickness of the upper platinum layer.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

<a href="/cs/project/GBP108%2F12%2FG108" target="_blank" >GBP108/12/G108: Příprava, modifikace a charakterizace materiálů zářením</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Physical Chemistry C

ISSN

1932-7447

e-ISSN

—

Svazek periodika

122

Číslo periodika v rámci svazku

46

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

26613-26622

Kód UT WoS článku

000451495600036

EID výsledku v databázi Scopus

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