Plasmon Catalysis on Bimetallic Surface-Selective Hydrogenationof Alkynes to Alkanes or Alkenes.
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F18%3A00507031" target="_blank" >RIV/67985858:_____/18:00507031 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/60461373:22310/18:43916447
Výsledek na webu
<a href="http://hdl.handle.net/11104/0298123" target="_blank" >http://hdl.handle.net/11104/0298123</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jpcc.8b07398" target="_blank" >10.1021/acs.jpcc.8b07398</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Plasmon Catalysis on Bimetallic Surface-Selective Hydrogenationof Alkynes to Alkanes or Alkenes.
Popis výsledku v původním jazyce
Utilization of plasmonics as a driving tool for chemical transformation triggering enables to achieve unprecedented results regarding photochemical conversion efficiency and chemical selectivity regulation. In this study, the bimetallic surface plasmon-polariton-supported grating is proposed as an effective background for plasmon-induced hydrogenation of alkynyl groups of absolute chemoselectivity. The periodical bimetallic structure consists of spatially modulated gold layers, covered with the nanometer-thick platinum layer. The alkyne bonds are covalently attached to the surface of the catalytic system through covalent grafting of the bimetallic surface with 4-ethynylbenzenediazonium tosylate, with triple bonds separated from the platinum layer by the benzene rings. The proposed bimetallic structure enables selective hydrogenation of alkyne bonds to alkenyl or alkyl moieties using cyclohexene as a hydrogen source. The selectivity of hydrogenation can be controlled by changing the structure parameters, for example, the thickness of the upper platinum layer.
Název v anglickém jazyce
Plasmon Catalysis on Bimetallic Surface-Selective Hydrogenationof Alkynes to Alkanes or Alkenes.
Popis výsledku anglicky
Utilization of plasmonics as a driving tool for chemical transformation triggering enables to achieve unprecedented results regarding photochemical conversion efficiency and chemical selectivity regulation. In this study, the bimetallic surface plasmon-polariton-supported grating is proposed as an effective background for plasmon-induced hydrogenation of alkynyl groups of absolute chemoselectivity. The periodical bimetallic structure consists of spatially modulated gold layers, covered with the nanometer-thick platinum layer. The alkyne bonds are covalently attached to the surface of the catalytic system through covalent grafting of the bimetallic surface with 4-ethynylbenzenediazonium tosylate, with triple bonds separated from the platinum layer by the benzene rings. The proposed bimetallic structure enables selective hydrogenation of alkyne bonds to alkenyl or alkyl moieties using cyclohexene as a hydrogen source. The selectivity of hydrogenation can be controlled by changing the structure parameters, for example, the thickness of the upper platinum layer.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10401 - Organic chemistry
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2018
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Physical Chemistry C
ISSN
1932-7447
e-ISSN
—
Svazek periodika
122
Číslo periodika v rámci svazku
46
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
10
Strana od-do
26613-26622
Kód UT WoS článku
000451495600036
EID výsledku v databázi Scopus
2-s2.0-85055495708