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A Ru/RuO2-Doped TiO2 Nanotubes as pH Sensors for Biomedical Applications: The Effect of the Amount and Oxidation of Deposited Ru on the Electrochemical Response

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43923465" target="_blank" >RIV/60461373:22310/21:43923465 - isvavai.cz</a>

  • Výsledek na webu

    <a href="https://www.ncbi.nlm.nih.gov/pubmed/34947506" target="_blank" >https://www.ncbi.nlm.nih.gov/pubmed/34947506</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/ma14247912" target="_blank" >10.3390/ma14247912</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    A Ru/RuO2-Doped TiO2 Nanotubes as pH Sensors for Biomedical Applications: The Effect of the Amount and Oxidation of Deposited Ru on the Electrochemical Response

  • Popis výsledku v původním jazyce

    In the field of orthopedic or dental implants, titanium and its alloys are most commonly used because of their excellent mechanical and corrosion properties and good biocompatibility. After implantation into the patient’s body, there is a high risk of developing bacterial inflammation, which negatively affects the surrounding tissues and the implant itself. Early detection of inflammation could be done with a pH sensor. In this work, pH-sensitive systems based on TiO2-Ru and TiO2-RuO2 combinations were fabricated and investigated. As a base material, Ti-6Al-4V alloy nanostructured by anodic oxidation was used. Ruthenium was successfully deposited on nanotubular TiO2 using cyclic polarization, galvanostatic and potentiostatic mode. Potentiostatic mode proved to be the most suitable. The selected samples were oxidized by cyclic polarization to form a TiO2-RuO2 system. The success of the oxidation was confirmed by XPS analysis. The electrochemical response of the systems to pH change was measured in saline solution using different techniques. The measurement of open circuit potential showed that unoxidized samples (TiO2-Ru) exhibited sub-Nernstian behavior (39.2 and 35.8 mV/pH). The oxidized sample (TiO2-RuO2) containing the highest amount of Ru exhibited super-Nernstian behavior (67.3 mV/pH). The Mott–Schottky analysis proved to be the best method. The use of the electrochemical impedance method can also be considered, provided that greater stability of the samples is achieved.

  • Název v anglickém jazyce

    A Ru/RuO2-Doped TiO2 Nanotubes as pH Sensors for Biomedical Applications: The Effect of the Amount and Oxidation of Deposited Ru on the Electrochemical Response

  • Popis výsledku anglicky

    In the field of orthopedic or dental implants, titanium and its alloys are most commonly used because of their excellent mechanical and corrosion properties and good biocompatibility. After implantation into the patient’s body, there is a high risk of developing bacterial inflammation, which negatively affects the surrounding tissues and the implant itself. Early detection of inflammation could be done with a pH sensor. In this work, pH-sensitive systems based on TiO2-Ru and TiO2-RuO2 combinations were fabricated and investigated. As a base material, Ti-6Al-4V alloy nanostructured by anodic oxidation was used. Ruthenium was successfully deposited on nanotubular TiO2 using cyclic polarization, galvanostatic and potentiostatic mode. Potentiostatic mode proved to be the most suitable. The selected samples were oxidized by cyclic polarization to form a TiO2-RuO2 system. The success of the oxidation was confirmed by XPS analysis. The electrochemical response of the systems to pH change was measured in saline solution using different techniques. The measurement of open circuit potential showed that unoxidized samples (TiO2-Ru) exhibited sub-Nernstian behavior (39.2 and 35.8 mV/pH). The oxidized sample (TiO2-RuO2) containing the highest amount of Ru exhibited super-Nernstian behavior (67.3 mV/pH). The Mott–Schottky analysis proved to be the best method. The use of the electrochemical impedance method can also be considered, provided that greater stability of the samples is achieved.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    20501 - Materials engineering

Návaznosti výsledku

  • Projekt

    <a href="/cs/project/NU20-06-00424" target="_blank" >NU20-06-00424: Implantabilní senzory pro včasnou detekci zánětu a bakteriální kolonizace</a><br>

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Ostatní

  • Rok uplatnění

    2021

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Materials

  • ISSN

    1996-1944

  • e-ISSN

  • Svazek periodika

    14

  • Číslo periodika v rámci svazku

    24

  • Stát vydavatele periodika

    CH - Švýcarská konfederace

  • Počet stran výsledku

    16

  • Strana od-do

    7912-7928

  • Kód UT WoS článku

    000744820300001

  • EID výsledku v databázi Scopus