Plasmon Coupling Inside 2D-like TiB2 Flakes for Water Splitting Half Reactions Enhancement in Acidic and Alkaline Conditions
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F22%3A43924750" target="_blank" >RIV/60461373:22310/22:43924750 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/68378271:_____/23:00564960 RIV/61388980:_____/23:00564960 RIV/44555601:13440/23:43897891
Výsledek na webu
<a href="https://doi.org/10.1016/j.cej.2022.140441" target="_blank" >https://doi.org/10.1016/j.cej.2022.140441</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cej.2022.140441" target="_blank" >10.1016/j.cej.2022.140441</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Plasmon Coupling Inside 2D-like TiB2 Flakes for Water Splitting Half Reactions Enhancement in Acidic and Alkaline Conditions
Popis výsledku v původním jazyce
Hybridization of catalytic and plasmon active materials provides an elegant way for efficiently improving of photo-electrochemical (PEC) water splitting. In this work, we propose the utilization of the plasmon coupling between surface plasmon polariton (SPP) and localized surface plasmon (LSP) for gigantic light concentration and triggering of the catalytic activity of titanium diboride (TiB2) flakes. The enhancement of TiB2 flakes' cat-alytic activity as a result of coupled plasmon triggering was investigated in PEC, including hydrogen and oxygen evolution half-reactions (HER and OER) performed in alkaline and acidic conditions. Additional studies per-formed at various light wavelengths and the time-dependent response of the structure show that the catalytic activity is triggered through the excitation of electron-hole pairs in TiB2 and their subsequent separation/ac-celeration in strong coupled plasmons field. In general, our work provides one of the first attempts how to realize a symmetric and less pH-sensitive catalyst for PEC water splitting.
Název v anglickém jazyce
Plasmon Coupling Inside 2D-like TiB2 Flakes for Water Splitting Half Reactions Enhancement in Acidic and Alkaline Conditions
Popis výsledku anglicky
Hybridization of catalytic and plasmon active materials provides an elegant way for efficiently improving of photo-electrochemical (PEC) water splitting. In this work, we propose the utilization of the plasmon coupling between surface plasmon polariton (SPP) and localized surface plasmon (LSP) for gigantic light concentration and triggering of the catalytic activity of titanium diboride (TiB2) flakes. The enhancement of TiB2 flakes' cat-alytic activity as a result of coupled plasmon triggering was investigated in PEC, including hydrogen and oxygen evolution half-reactions (HER and OER) performed in alkaline and acidic conditions. Additional studies per-formed at various light wavelengths and the time-dependent response of the structure show that the catalytic activity is triggered through the excitation of electron-hole pairs in TiB2 and their subsequent separation/ac-celeration in strong coupled plasmons field. In general, our work provides one of the first attempts how to realize a symmetric and less pH-sensitive catalyst for PEC water splitting.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20501 - Materials engineering
Návaznosti výsledku
Projekt
<a href="/cs/project/GA21-09277S" target="_blank" >GA21-09277S: MXene: plazmonicky asistovaná modifikace povrchu a optimalizace jeho vlastností</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2022
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Chemical Engineering Journal
ISSN
1385-8947
e-ISSN
—
Svazek periodika
454
Číslo periodika v rámci svazku
3
Stát vydavatele periodika
CH - Švýcarská konfederace
Počet stran výsledku
11
Strana od-do
"140441/1"-11
Kód UT WoS článku
000895276400001
EID výsledku v databázi Scopus
—