Plasmon coupling inside 2D-like TiB2 flakes for water splitting half reactions enhancement in acidic and alkaline conditions

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F23%3A00564960" target="_blank" >RIV/61388980:_____/23:00564960 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22310/22:43924750 RIV/68378271:_____/23:00564960 RIV/44555601:13440/23:43897891

Výsledek na webu

<a href="https://doi.org/10.1016/j.cej.2022.140441" target="_blank" >https://doi.org/10.1016/j.cej.2022.140441</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.cej.2022.140441" target="_blank" >10.1016/j.cej.2022.140441</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Plasmon coupling inside 2D-like TiB2 flakes for water splitting half reactions enhancement in acidic and alkaline conditions

Popis výsledku v původním jazyce

Hybridization of catalytic and plasmon active materials provides an elegant way for efficiently improving of photo-electrochemical (PEC) water splitting. In this work, we propose the utilization of the plasmon coupling between surface plasmon polariton (SPP) and localized surface plasmon (LSP) for gigantic light concentration and triggering of the catalytic activity of titanium diboride (TiB2) flakes. The enhancement of TiB2 flakes' catalytic activity as a result of coupled plasmon triggering was investigated in PEC, including hydrogen and oxygen evolution half-reactions (HER and OER) performed in alkaline and acidic conditions. Additional studies performed at various light wavelengths and the time-dependent response of the structure show that the catalytic activity is triggered through the excitation of electron-hole pairs in TiB2 and their subsequent separation/acceleration in strong coupled plasmons field. In general, our work provides one of the first attempts how to realize a symmetric and less pH-sensitive catalyst for PEC water splitting.

Název v anglickém jazyce

Plasmon coupling inside 2D-like TiB2 flakes for water splitting half reactions enhancement in acidic and alkaline conditions

Popis výsledku anglicky

Hybridization of catalytic and plasmon active materials provides an elegant way for efficiently improving of photo-electrochemical (PEC) water splitting. In this work, we propose the utilization of the plasmon coupling between surface plasmon polariton (SPP) and localized surface plasmon (LSP) for gigantic light concentration and triggering of the catalytic activity of titanium diboride (TiB2) flakes. The enhancement of TiB2 flakes' catalytic activity as a result of coupled plasmon triggering was investigated in PEC, including hydrogen and oxygen evolution half-reactions (HER and OER) performed in alkaline and acidic conditions. Additional studies performed at various light wavelengths and the time-dependent response of the structure show that the catalytic activity is triggered through the excitation of electron-hole pairs in TiB2 and their subsequent separation/acceleration in strong coupled plasmons field. In general, our work provides one of the first attempts how to realize a symmetric and less pH-sensitive catalyst for PEC water splitting.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GA21-09277S" target="_blank" >GA21-09277S: MXene: plazmonicky asistovaná modifikace povrchu a optimalizace jeho vlastností</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Chemical Engineering Journal

ISSN

1385-8947

e-ISSN

1873-3212

Svazek periodika

454

Číslo periodika v rámci svazku

FEB

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

140441

Kód UT WoS článku

000895276400001

EID výsledku v databázi Scopus

2-s2.0-85142204123