Topochemical Transformation of Two-Dimensional VSe2 into Metallic Nonlayered VO2for Water Splitting Reactions in Acidic and Alkaline Media

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F22%3A43925970" target="_blank" >RIV/60461373:22310/22:43925970 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.acs.org/doi/full/10.1021/acsnano.1c06662" target="_blank" >https://pubs.acs.org/doi/full/10.1021/acsnano.1c06662</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsnano.1c06662" target="_blank" >10.1021/acsnano.1c06662</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Topochemical Transformation of Two-Dimensional VSe2 into Metallic Nonlayered VO2for Water Splitting Reactions in Acidic and Alkaline Media

Popis výsledku v původním jazyce

The engineering of the structural and morphological properties of nanomaterials is a fundamental aspect to attain desired performance in energy storage/conversion systems and multifunctional composites. We report the synthesis of room temperature-stable metallic rutile VO2 (VO2 (R)) nanosheets by topochemically transforming liquid-phase exfoliated VSe2 in a reductive Ar-H2 atmosphere. The as-produced VO2 (R) represents an example of two-dimensional (2D) nonlayered materials, whose bulk counterparts do not have a layered structure composed by layers held together by van der Waals force or electrostatic forces between charged layers and counterbalancing ions amid them. By pretreating the VSe2 nanosheets by O2 plasma, the resulting 2D VO2 (R) nanosheets exhibit a porous morphology that increases the material specific surface area while introducing defective sites. The as-synthesized porous (holey)-VO2 (R) nanosheets are investigated as metallic catalysts for the water splitting reactions in both acidic and alkaline media, reaching a maximum mass activity of 972.3 A g-1 at -0.300 V vs RHE for the hydrogen evolution reaction (HER) in 0.5 M H2SO4 (faradaic efficiency = 100%, overpotential for the HER at 10 mA cm-2 = 0.184 V) and a mass activity (calculated for a non 100% faradaic efficiency) of 745.9 A g-1 at +1.580 V vs RHE for the oxygen evolution reaction (OER) in 1 M KOH (overpotential for the OER at 10 mA cm-2 = 0.209 V). By demonstrating proof-of-concept electrolyzers, our results show the possibility to synthesize special material phases through topochemical conversion of 2D materials for advanced energy-related applications. © 2022 American Chemical Society. All rights reserved.

Název v anglickém jazyce

Topochemical Transformation of Two-Dimensional VSe2 into Metallic Nonlayered VO2for Water Splitting Reactions in Acidic and Alkaline Media

Popis výsledku anglicky

The engineering of the structural and morphological properties of nanomaterials is a fundamental aspect to attain desired performance in energy storage/conversion systems and multifunctional composites. We report the synthesis of room temperature-stable metallic rutile VO2 (VO2 (R)) nanosheets by topochemically transforming liquid-phase exfoliated VSe2 in a reductive Ar-H2 atmosphere. The as-produced VO2 (R) represents an example of two-dimensional (2D) nonlayered materials, whose bulk counterparts do not have a layered structure composed by layers held together by van der Waals force or electrostatic forces between charged layers and counterbalancing ions amid them. By pretreating the VSe2 nanosheets by O2 plasma, the resulting 2D VO2 (R) nanosheets exhibit a porous morphology that increases the material specific surface area while introducing defective sites. The as-synthesized porous (holey)-VO2 (R) nanosheets are investigated as metallic catalysts for the water splitting reactions in both acidic and alkaline media, reaching a maximum mass activity of 972.3 A g-1 at -0.300 V vs RHE for the hydrogen evolution reaction (HER) in 0.5 M H2SO4 (faradaic efficiency = 100%, overpotential for the HER at 10 mA cm-2 = 0.184 V) and a mass activity (calculated for a non 100% faradaic efficiency) of 745.9 A g-1 at +1.580 V vs RHE for the oxygen evolution reaction (OER) in 1 M KOH (overpotential for the OER at 10 mA cm-2 = 0.209 V). By demonstrating proof-of-concept electrolyzers, our results show the possibility to synthesize special material phases through topochemical conversion of 2D materials for advanced energy-related applications. © 2022 American Chemical Society. All rights reserved.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Nano

ISSN

1936-0851

e-ISSN

1936-086X

Svazek periodika

16

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

17

Strana od-do

351-367

Kód UT WoS článku

000736824500001

EID výsledku v databázi Scopus

2-s2.0-85122405270