New Sn-Mg-Al hydrotalcite-based catalysts for Baeyer-Villiger oxidation of β-cyclocitral

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43927746" target="_blank" >RIV/60461373:22310/23:43927746 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0920586123004649?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0920586123004649?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.cattod.2023.114440" target="_blank" >10.1016/j.cattod.2023.114440</a>

Jazyk výsledku

angličtina

Název v původním jazyce

New Sn-Mg-Al hydrotalcite-based catalysts for Baeyer-Villiger oxidation of β-cyclocitral

Popis výsledku v původním jazyce

This study focuses on the Baeyer-Villiger (BV) oxidation of β-cyclocitral using tin-modified mixed oxides based on hydrotalcites as catalysts. Hydrotalcite-like compounds modified with tin were found to be promising catalysts capable of catalyzing both BV oxidation and subsequent hydrolysis of formed formate. The testing of catalytic activity and optimization of reaction conditions for achieving high conversion and selectivity to the desired product, 2,6,6-trimethylcyclohexanone, was carried out. The effects of the Mg/Al ions molar ratio, tin amount, catalyst amount, and form (hydrotalcite or mixed oxide) on the reaction course and selectivity to 2,6,6-trimethylcyclohexanone were studied. Optimal reaction conditions (temperature, reactant ratio, solvent type and amount) were determined. Additionally, different dosing methods, amounts and types of oxidizing agents were tested. The reaction was successfully scaled up, and the possibility of reusing the catalyst at least three times was confirmed. Gradual dosing of 6.4 molar equivalents of 50% hydrogen peroxide in 24 doses during 5-minute intervals over 115 min was determined as the most suitable method. The temperature of 115 °C, cyclohexanol in a mass ratio of 2:1 to the starting material as a solvent, and 15 wt% of the catalyst to the starting material was identified as optimal for the BV oxidation of ß-cyclocitral. The mixed oxide with a Mg/Al molar ratio of 2 impregnated with 3 wt% tin at room temperature (3Sn-MO2imp25) exhibited the highest activity and selectivity towards 2,6,6-trimethylcyclohexanone. Under these reaction conditions, total conversion and a 60% selectivity to the desired product were achieved after 5 h of reaction. © 2023 Elsevier B.V.

Název v anglickém jazyce

New Sn-Mg-Al hydrotalcite-based catalysts for Baeyer-Villiger oxidation of β-cyclocitral

Popis výsledku anglicky

This study focuses on the Baeyer-Villiger (BV) oxidation of β-cyclocitral using tin-modified mixed oxides based on hydrotalcites as catalysts. Hydrotalcite-like compounds modified with tin were found to be promising catalysts capable of catalyzing both BV oxidation and subsequent hydrolysis of formed formate. The testing of catalytic activity and optimization of reaction conditions for achieving high conversion and selectivity to the desired product, 2,6,6-trimethylcyclohexanone, was carried out. The effects of the Mg/Al ions molar ratio, tin amount, catalyst amount, and form (hydrotalcite or mixed oxide) on the reaction course and selectivity to 2,6,6-trimethylcyclohexanone were studied. Optimal reaction conditions (temperature, reactant ratio, solvent type and amount) were determined. Additionally, different dosing methods, amounts and types of oxidizing agents were tested. The reaction was successfully scaled up, and the possibility of reusing the catalyst at least three times was confirmed. Gradual dosing of 6.4 molar equivalents of 50% hydrogen peroxide in 24 doses during 5-minute intervals over 115 min was determined as the most suitable method. The temperature of 115 °C, cyclohexanol in a mass ratio of 2:1 to the starting material as a solvent, and 15 wt% of the catalyst to the starting material was identified as optimal for the BV oxidation of ß-cyclocitral. The mixed oxide with a Mg/Al molar ratio of 2 impregnated with 3 wt% tin at room temperature (3Sn-MO2imp25) exhibited the highest activity and selectivity towards 2,6,6-trimethylcyclohexanone. Under these reaction conditions, total conversion and a 60% selectivity to the desired product were achieved after 5 h of reaction. © 2023 Elsevier B.V.

Druh

J_SC - Článek v periodiku v databázi SCOPUS

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

CATALYSIS TODAY

ISSN

0920-5861

e-ISSN

—

Svazek periodika

427

Číslo periodika v rámci svazku

2024

Stát vydavatele periodika

ZA - Jihoafrická republika

Počet stran výsledku

12

Strana od-do

—

Kód UT WoS článku

—

EID výsledku v databázi Scopus

2-s2.0-85175567446