Gas Phase Photocatalysis on Large-Scale TiO2 Nanotube Layers for Pollutant Degradation: Influence of the Nanotube Crystallinity

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43927881" target="_blank" >RIV/60461373:22310/23:43927881 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216275:25310/23:39920395 RIV/60461373:22350/23:43927881

Výsledek na webu

<a href="https://pubs.acs.org/doi/pdf/10.1021/acsanm.3c03199?src=getftr" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acsanm.3c03199?src=getftr</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsanm.3c03199" target="_blank" >10.1021/acsanm.3c03199</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Gas Phase Photocatalysis on Large-Scale TiO2 Nanotube Layers for Pollutant Degradation: Influence of the Nanotube Crystallinity

Popis výsledku v původním jazyce

In this work, for the first time, the influence of the crystallinity of TiO2 nanotube (TNT) layers on their gas phase photocatalytic performance was investigated under ISO standards using two distinct model pollutants, namely, hexane and acetaldehyde. TNT layers (1 μm thick) on 5 × 10 cm2 large Ti substrates were employed in this work due to their excellent adhesion to Ti upon annealing at high temperatures. Annealing of the TNT layers was carried out in a temperature range between 300 and 700 °C, resulting in TNT layers with different crystallinities, i.e., from the pure anatase phase to an 85% rutile phase. The superior performance of the TNT layers annealed at 600 °C with mixed anatase and rutile phase compared to other specimens was observed for both model pollutants, stemming from the band alignment between the two crystalline phases. For higher annealing temperatures, however, the photocatalytic performance of the TNT layers was reduced due to a partial disintegration of the TNTs. No surface contamination of the TNT layers with residues of pollutant degradation products was observed after experiments. © 2023 The Authors. Published by American Chemical Society.

Název v anglickém jazyce

Gas Phase Photocatalysis on Large-Scale TiO2 Nanotube Layers for Pollutant Degradation: Influence of the Nanotube Crystallinity

Popis výsledku anglicky

In this work, for the first time, the influence of the crystallinity of TiO2 nanotube (TNT) layers on their gas phase photocatalytic performance was investigated under ISO standards using two distinct model pollutants, namely, hexane and acetaldehyde. TNT layers (1 μm thick) on 5 × 10 cm2 large Ti substrates were employed in this work due to their excellent adhesion to Ti upon annealing at high temperatures. Annealing of the TNT layers was carried out in a temperature range between 300 and 700 °C, resulting in TNT layers with different crystallinities, i.e., from the pure anatase phase to an 85% rutile phase. The superior performance of the TNT layers annealed at 600 °C with mixed anatase and rutile phase compared to other specimens was observed for both model pollutants, stemming from the band alignment between the two crystalline phases. For higher annealing temperatures, however, the photocatalytic performance of the TNT layers was reduced due to a partial disintegration of the TNTs. No surface contamination of the TNT layers with residues of pollutant degradation products was observed after experiments. © 2023 The Authors. Published by American Chemical Society.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GA21-27243S" target="_blank" >GA21-27243S: Syntéza TiO2 nanotrubicových vrstev o velké ploše pro efektivní fotokatalytickou degradaci polutantů v plynné fázi a virů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Applied Nano Materials

ISSN

2574-0970

e-ISSN

—

Svazek periodika

6

Číslo periodika v rámci svazku

18

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

7

Strana od-do

17053-17059

Kód UT WoS článku

001079143300001

EID výsledku v databázi Scopus

2-s2.0-85173151476