High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F23%3A43933964" target="_blank" >RIV/60461373:22310/23:43933964 - isvavai.cz</a>

Výsledek na webu

<a href="https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202214078" target="_blank" >https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202214078</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/adfm.202214078" target="_blank" >10.1002/adfm.202214078</a>

Jazyk výsledku

angličtina

Název v původním jazyce

High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal

Popis výsledku v původním jazyce

3D organic-inorganic metal halide perovskites are excellent materials for optoelectronic applications due to their exceptional properties, solution processability, and cost-effectiveness. However, the lack of environmental stability highly restricts them from practical applications. Herein, a stable centimeter-long 2D hybrid perovskite (N-MPDA)[PbBr4] single crystal using divalent N1-methylpropane-1,3-diammonium (N-MPDA) cation as an organic spacer, is reported. The as-grown single crystal exhibits stable optoelectronic performance, low threshold random lasing, and multi-photon luminescence/multi-harmonic generation. A photoconductive device fabricated using (N-MPDA)[PbBr4] single crystal exhibits an excellent photoresponsivity (approximate to 124 AW(-1) at 405 nm) that is approximate to 4 orders of magnitudes higher than that of monovalent organic spacer-assisted 2D perovskites, such as (BA)(2)PbBr4 and (PEA)(2)PbBr4, and large specific detectivity (approximate to 10(12) Jones). As an optical gain media, the (N-MPDA)[PbBr4] single crystal exhibits a low threshold random lasing (approximate to 6.5 mu J cm(-2)) with angular dependent narrow linewidth (approximate to 0.1 nm) and high-quality factor (Q approximate to 2673). Based on these results, the outstanding optoelectronic merits of (N-MPDA)[PbBr4] single crystal will offer a high-performance device and act as a dynamic material to construct stable future electronics and optoelectronic-based applications.

Název v anglickém jazyce

High-Performance Photodetector and Angular-Dependent Random Lasing from Long-Chain Organic Diammonium Sandwiched 2D Hybrid Perovskite Non-Linear Optical Single Crystal

Popis výsledku anglicky

3D organic-inorganic metal halide perovskites are excellent materials for optoelectronic applications due to their exceptional properties, solution processability, and cost-effectiveness. However, the lack of environmental stability highly restricts them from practical applications. Herein, a stable centimeter-long 2D hybrid perovskite (N-MPDA)[PbBr4] single crystal using divalent N1-methylpropane-1,3-diammonium (N-MPDA) cation as an organic spacer, is reported. The as-grown single crystal exhibits stable optoelectronic performance, low threshold random lasing, and multi-photon luminescence/multi-harmonic generation. A photoconductive device fabricated using (N-MPDA)[PbBr4] single crystal exhibits an excellent photoresponsivity (approximate to 124 AW(-1) at 405 nm) that is approximate to 4 orders of magnitudes higher than that of monovalent organic spacer-assisted 2D perovskites, such as (BA)(2)PbBr4 and (PEA)(2)PbBr4, and large specific detectivity (approximate to 10(12) Jones). As an optical gain media, the (N-MPDA)[PbBr4] single crystal exhibits a low threshold random lasing (approximate to 6.5 mu J cm(-2)) with angular dependent narrow linewidth (approximate to 0.1 nm) and high-quality factor (Q approximate to 2673). Based on these results, the outstanding optoelectronic merits of (N-MPDA)[PbBr4] single crystal will offer a high-performance device and act as a dynamic material to construct stable future electronics and optoelectronic-based applications.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ADVANCED FUNCTIONAL MATERIALS

ISSN

1616-301X

e-ISSN

1616-3028

Svazek periodika

33

Číslo periodika v rámci svazku

17

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

10

Strana od-do

2214078

Kód UT WoS článku

000928813000001

EID výsledku v databázi Scopus

2-s2.0-85147504234