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Chemiresistors based on li-doped cuo–tio2 films

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F21%3A43922954" target="_blank" >RIV/60461373:22340/21:43922954 - isvavai.cz</a>

  • Nalezeny alternativní kódy

    RIV/67985882:_____/21:00546331 RIV/61389005:_____/21:00546331

  • Výsledek na webu

    <a href="https://www.mdpi.com/2227-9040/9/9/246" target="_blank" >https://www.mdpi.com/2227-9040/9/9/246</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/chemosensors9090246" target="_blank" >10.3390/chemosensors9090246</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Chemiresistors based on li-doped cuo–tio2 films

  • Popis výsledku v původním jazyce

    Chemiresistors based on thin films of the Li-doped CuO–TiO2 heterojunctions were synthesized by a 2-step method: (i) repeated ion beam sputtering of the building elements (on the Si substrates and multisensor platforms); and (ii) thermal annealing in flowing air. The structure and composition of the films were analyzed by several methods: Rutherford Backscattering (RBS), Neutron Depth Profiling (NDP), Secondary Ion Mass Spectrometry (SIMS), and Atomic Force Microscopy (AFM), and their sensitivity to gaseous analytes was evaluated using a specific lab-made device operating in a continuous gas flow mode. The obtained results showed that the Li doping significantly increased the sensitivity of the sensors to oxidizing gases, such as NO2, O3, and Cl2, but not to reducing H2 . The sensing response of the CuO–TiO2–Li chemiresistors improved with increasing Li content. For the best sensors with about 15% Li atoms, the detection limits were as follows: NO2 → 0.5 ppm, O3 → 10 ppb, and Cl2 → 0.1 ppm. The Li-doped sensors showed excellent sensing performance at a lower operating temperature (200◦C); however, even though their response time was only a few minutes, their recovery was slow (up to a few hours) and incomplete. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

  • Název v anglickém jazyce

    Chemiresistors based on li-doped cuo–tio2 films

  • Popis výsledku anglicky

    Chemiresistors based on thin films of the Li-doped CuO–TiO2 heterojunctions were synthesized by a 2-step method: (i) repeated ion beam sputtering of the building elements (on the Si substrates and multisensor platforms); and (ii) thermal annealing in flowing air. The structure and composition of the films were analyzed by several methods: Rutherford Backscattering (RBS), Neutron Depth Profiling (NDP), Secondary Ion Mass Spectrometry (SIMS), and Atomic Force Microscopy (AFM), and their sensitivity to gaseous analytes was evaluated using a specific lab-made device operating in a continuous gas flow mode. The obtained results showed that the Li doping significantly increased the sensitivity of the sensors to oxidizing gases, such as NO2, O3, and Cl2, but not to reducing H2 . The sensing response of the CuO–TiO2–Li chemiresistors improved with increasing Li content. For the best sensors with about 15% Li atoms, the detection limits were as follows: NO2 → 0.5 ppm, O3 → 10 ppb, and Cl2 → 0.1 ppm. The Li-doped sensors showed excellent sensing performance at a lower operating temperature (200◦C); however, even though their response time was only a few minutes, their recovery was slow (up to a few hours) and incomplete. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    21001 - Nano-materials (production and properties)

Návaznosti výsledku

  • Projekt

    <a href="/cs/project/GA19-02804S" target="_blank" >GA19-02804S: Nanostrukturované heteropřechody pro chemirezistory</a><br>

  • Návaznosti

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Ostatní

  • Rok uplatnění

    2021

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    Chemosensors

  • ISSN

    2227-9040

  • e-ISSN

  • Svazek periodika

    9

  • Číslo periodika v rámci svazku

    9

  • Stát vydavatele periodika

    CH - Švýcarská konfederace

  • Počet stran výsledku

    20

  • Strana od-do

  • Kód UT WoS článku

    000699256200001

  • EID výsledku v databázi Scopus

    2-s2.0-85114992369