Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)center dot H2O

Kód výsledku v IS VaVaI

RIV/60461446:52810/11:#0000097 - isvavai.cz

Výsledek na webu

http://onlinelibrary.wiley.com/doi/10.1002/crat.201100262/abstract

DOI - Digital Object Identifier

10.1002/crat.201100262

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)center dot H2O

Popis výsledku v původním jazyce

Single-crystals of the layered copper hydroxide acetate Cu(2)(OH)(3)(CH(3)COO)center dot H(2)O were synthesized by heating copper acetate solution at 60 degrees C. The standard synthesis of the title compound based on slow titration of copper acetate solution with NaOH yielded materials with worse morphology and an additional phase present. The obtained products were characterized with powder X-ray diffraction, high temperature powder X-ray diffraction, scanning electron microscopy and infrared spectroscopy. The crystal structure was determined from single-crystal X-ray diffraction data, collected both at 120 K and at 293 K. The title compound crystallizes in the monoclinic botallackite-type layered structure, space group P2(1), with the lattice parameters a = 5.5776(3) angstrom, b = 6.0733(2) angstrom, c = 18.5134(8) angstrom, beta = 91.802(4)degrees and a = 5.5875(4) angstrom, b = 6.0987(4) angstrom, c = 18.6801(10) angstrom, beta = 91.934(5)degrees for 120 K and for 293 K, respectiv

Název v anglickém jazyce

Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)center dot H2O

Popis výsledku anglicky

Single-crystals of the layered copper hydroxide acetate Cu(2)(OH)(3)(CH(3)COO)center dot H(2)O were synthesized by heating copper acetate solution at 60 degrees C. The standard synthesis of the title compound based on slow titration of copper acetate solution with NaOH yielded materials with worse morphology and an additional phase present. The obtained products were characterized with powder X-ray diffraction, high temperature powder X-ray diffraction, scanning electron microscopy and infrared spectroscopy. The crystal structure was determined from single-crystal X-ray diffraction data, collected both at 120 K and at 293 K. The title compound crystallizes in the monoclinic botallackite-type layered structure, space group P2(1), with the lattice parameters a = 5.5776(3) angstrom, b = 6.0733(2) angstrom, c = 18.5134(8) angstrom, beta = 91.802(4)degrees and a = 5.5875(4) angstrom, b = 6.0987(4) angstrom, c = 18.6801(10) angstrom, beta = 91.934(5)degrees for 120 K and for 293 K, respectiv

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

AL - Umění, architektura, kulturní dědictví

OECD FORD obor

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Projekt

—

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

CRYSTAL RESEARCH AND TECHNOLOGY

ISSN

0232-1300

e-ISSN

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Svazek periodika

46

Číslo periodika v rámci svazku

10

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

7

Strana od-do

1051-1057

Kód UT WoS článku

000295315900007

EID výsledku v databázi Scopus

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