Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F11%3A00368900" target="_blank" >RIV/68378271:_____/11:00368900 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/61388980:_____/11:00368900
Výsledek na webu
<a href="http://dx.doi.org/10.1002/crat.201100262" target="_blank" >http://dx.doi.org/10.1002/crat.201100262</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/crat.201100262" target="_blank" >10.1002/crat.201100262</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O
Popis výsledku v původním jazyce
Single-crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O were synthesized by heating copper acetate solution at 60°C. The standard synthesis of the title compound based on slow titration of copper acetate solution with NaOH yielded materials with worse morphology and an additional phase present. The obtained products were characterised with powder X-ray diffraction, high temperature powder X-ray diffraction, scanning electron microscopy and infrared spectroscopy. The crystal structurewas determined from single-crystal X-ray diffraction data, collected both at 120 K and at 293 K. The title compound crystallizes in the monoclinic botallackite-type layered structure, with the lattice parameters a = 5.5776(3) ?, b = 6.0733(2) ?, c = 18.5134(8) ?, beta = 91.802(4)° and a = 5.5875(4)?, b = 6.0987(4)?, c = 18.6801(10)?, beta = 91.934(5)° for 120 K and for 293 K, respectively. Acetate groups and water molecules are interlayered between corrugated sheets of edge-sharing CuO6
Název v anglickém jazyce
Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O
Popis výsledku anglicky
Single-crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O were synthesized by heating copper acetate solution at 60°C. The standard synthesis of the title compound based on slow titration of copper acetate solution with NaOH yielded materials with worse morphology and an additional phase present. The obtained products were characterised with powder X-ray diffraction, high temperature powder X-ray diffraction, scanning electron microscopy and infrared spectroscopy. The crystal structurewas determined from single-crystal X-ray diffraction data, collected both at 120 K and at 293 K. The title compound crystallizes in the monoclinic botallackite-type layered structure, with the lattice parameters a = 5.5776(3) ?, b = 6.0733(2) ?, c = 18.5134(8) ?, beta = 91.802(4)° and a = 5.5875(4)?, b = 6.0987(4)?, c = 18.6801(10)?, beta = 91.934(5)° for 120 K and for 293 K, respectively. Acetate groups and water molecules are interlayered between corrugated sheets of edge-sharing CuO6
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CA - Anorganická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
Z - Vyzkumny zamer (s odkazem do CEZ)
Ostatní
Rok uplatnění
2011
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Crystal Research and Technology
ISSN
0232-1300
e-ISSN
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Svazek periodika
46
Číslo periodika v rámci svazku
10
Stát vydavatele periodika
DE - Spolková republika Německo
Počet stran výsledku
7
Strana od-do
1051-1057
Kód UT WoS článku
000295315900007
EID výsledku v databázi Scopus
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