Selected Ion Flow Tube Studies of the Reactions of H3O+, NO+ and O2+ with the Anaesthetic Gases Halothane, Isoflurane and Sevoflurane.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020157" target="_blank" >RIV/61388955:_____/02:54020157 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Selected Ion Flow Tube Studies of the Reactions of H3O+, NO+ and O2+ with the Anaesthetic Gases Halothane, Isoflurane and Sevoflurane.

Popis výsledku v původním jazyce

We have carried out a study of the reactions of H3O+, NO+ and O2+, the commonly used precursor ions for SIFT-MS, with three anaesthetic gases, halothane, isoflurane and sevoflurane. The motivation for this study was to provide the necessary kinetic datathat would allow the quantification of these anaesthetic gases in operating theatre air and in the breath of theatre staff and post-operative patients. A clear negative result from these experiments is that NO+, although undergoing the simplest chemistryis unsuitable for this SIFT-MS application. However, although the ion chemistry of the H3O+ and O2+ with these compounds is very complex, there being several product ions in each reaction, many of which react rapidly with water molecules, monitor ionnshave been identified for all three anaesthetic gases when using H3O+ and O2+ as precursor ions. The detailed ion chemistry is discussed and the specific monitor ions are indicated.

Název v anglickém jazyce

Selected Ion Flow Tube Studies of the Reactions of H3O+, NO+ and O2+ with the Anaesthetic Gases Halothane, Isoflurane and Sevoflurane.

Popis výsledku anglicky

We have carried out a study of the reactions of H3O+, NO+ and O2+, the commonly used precursor ions for SIFT-MS, with three anaesthetic gases, halothane, isoflurane and sevoflurane. The motivation for this study was to provide the necessary kinetic datathat would allow the quantification of these anaesthetic gases in operating theatre air and in the breath of theatre staff and post-operative patients. A clear negative result from these experiments is that NO+, although undergoing the simplest chemistryis unsuitable for this SIFT-MS application. However, although the ion chemistry of the H3O+ and O2+ with these compounds is very complex, there being several product ions in each reaction, many of which react rapidly with water molecules, monitor ionnshave been identified for all three anaesthetic gases when using H3O+ and O2+ as precursor ions. The detailed ion chemistry is discussed and the specific monitor ions are indicated.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2002

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Rapid Communications in Mass Spectrometry

ISSN

0951-4198

e-ISSN

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Svazek periodika

16

Číslo periodika v rámci svazku

N/A

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

1860-1870

Kód UT WoS článku

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EID výsledku v databázi Scopus

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