Intercalation chemistry of layered zeolite precursor IPC-1P

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00427875" target="_blank" >RIV/61388955:_____/14:00427875 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.cattod.2013.10.051" target="_blank" >http://dx.doi.org/10.1016/j.cattod.2013.10.051</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.cattod.2013.10.051" target="_blank" >10.1016/j.cattod.2013.10.051</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Intercalation chemistry of layered zeolite precursor IPC-1P

Popis výsledku v původním jazyce

Lamellar zeolites like layered IPC-1 precursor, IPC-1P, offer unprecedented opportunities for creating diversity of more open zeolite structures prepared post-synthesis by expanding and modifying the interlamellar space. The present study investigates the intercalation chemistry of IPC-1P as a possible way to produce new expanded materials. Layered precursor IPC-1P obtained by 'top-down' modification of UTL germanosilicate was intercalated with different organic agents followed by stabilization and pillaring. Prepared materials were evaluated by X-ray powder diffraction, sorption of nitrogen and scanning electron microscopy. The d-spacing of intercalated precursor - IPC-1P (organic) - was in the range between 1.04 and 3.63 nm. Calcination of intercalated precursors provided mainly IPC-2 and IPC4 zeolites. We demonstrate that stabilization of IPC-1P with organic species can produce new, more expanded structures than previously known IPC-2 zeolite. The pillaring of IPC-1P intercalated wi

Název v anglickém jazyce

Intercalation chemistry of layered zeolite precursor IPC-1P

Popis výsledku anglicky

Lamellar zeolites like layered IPC-1 precursor, IPC-1P, offer unprecedented opportunities for creating diversity of more open zeolite structures prepared post-synthesis by expanding and modifying the interlamellar space. The present study investigates the intercalation chemistry of IPC-1P as a possible way to produce new expanded materials. Layered precursor IPC-1P obtained by 'top-down' modification of UTL germanosilicate was intercalated with different organic agents followed by stabilization and pillaring. Prepared materials were evaluated by X-ray powder diffraction, sorption of nitrogen and scanning electron microscopy. The d-spacing of intercalated precursor - IPC-1P (organic) - was in the range between 1.04 and 3.63 nm. Calcination of intercalated precursors provided mainly IPC-2 and IPC4 zeolites. We demonstrate that stabilization of IPC-1P with organic species can produce new, more expanded structures than previously known IPC-2 zeolite. The pillaring of IPC-1P intercalated wi

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GAP106%2F12%2F0189" target="_blank" >GAP106/12/0189: Dvojrozměrné zeolity s říditelnou architekturou</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysis Today

ISSN

0920-5861

e-ISSN

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Svazek periodika

227

Číslo periodika v rámci svazku

MAY 2014

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

8

Strana od-do

37-44

Kód UT WoS článku

000332412900007

EID výsledku v databázi Scopus

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