Electrochemical and Spectrophotometric Study of the Hydration of Orthophthalaldehyde and Its Reaction with Amines and Amino Acids

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00446947" target="_blank" >RIV/61388955:_____/15:00446947 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1149/06626.0013ecst" target="_blank" >http://dx.doi.org/10.1149/06626.0013ecst</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1149/06626.0013ecst" target="_blank" >10.1149/06626.0013ecst</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Electrochemical and Spectrophotometric Study of the Hydration of Orthophthalaldehyde and Its Reaction with Amines and Amino Acids

Popis výsledku v původním jazyce

Reactions of orthophthalaldehyde (OPA) with aliphatic ?-amino acids and with aliphatic primary amines were studied in buffered aqueous solution and in non-aqueous acetonitrile. For comparison lysine and glycine ethyl ester were used. The role of the substitution on the ?-carbon was discovered and the effect of OPA hydration on the course of the reaction was also investigated. In contrary to the published information, the dialdehydic unhydrated form is not the primary reactive species and for the successful reaction of OPA with amines, the presence of water is necessary.

Název v anglickém jazyce

Electrochemical and Spectrophotometric Study of the Hydration of Orthophthalaldehyde and Its Reaction with Amines and Amino Acids

Popis výsledku anglicky

Reactions of orthophthalaldehyde (OPA) with aliphatic ?-amino acids and with aliphatic primary amines were studied in buffered aqueous solution and in non-aqueous acetonitrile. For comparison lysine and glycine ethyl ester were used. The role of the substitution on the ?-carbon was discovered and the effect of OPA hydration on the course of the reaction was also investigated. In contrary to the published information, the dialdehydic unhydrated form is not the primary reactive species and for the successful reaction of OPA with amines, the presence of water is necessary.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CG - Elektrochemie

OECD FORD obor

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Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ECS Transactions

ISSN

1938-5862

e-ISSN

—

Svazek periodika

66

Číslo periodika v rámci svazku

26

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

9

Strana od-do

13-22

Kód UT WoS článku

—

EID výsledku v databázi Scopus

2-s2.0-84940377798