Ion chemistry at elevated ion–molecule interaction energies in a selected ion flow-drift tube: reactions of H3O+, NO+ and O2+ with saturated aliphatic ketones

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00482892" target="_blank" >RIV/61388955:_____/17:00482892 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1039/C7CP05795D" target="_blank" >http://dx.doi.org/10.1039/C7CP05795D</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C7CP05795D" target="_blank" >10.1039/C7CP05795D</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Ion chemistry at elevated ion–molecule interaction energies in a selected ion flow-drift tube: reactions of H3O+, NO+ and O2+ with saturated aliphatic ketones

Popis výsledku v původním jazyce

The reactions of H3O+, NO+ and O2+ ions with a homologous series of six aliphatic ketones, viz. acetone through 2-octanone, have been investigated in a helium-buffered selected ion flow-drift tube, SIFDT, in order to reveal their dependencies on ion–molecule interaction energies, Er, and to gain insight into their mechanisms. The ultimate motivation is to allow analysis and absolute quantification of trace amounts of ketones and other volatile organic compounds in air using selected ion flow-drift tube mass spectrometry, SIFDT-MS. The reactions of H3O+ with the ketone molecules, M, proceed via exothermic proton transfer producing MH+ ions, the collisional rate coefficients, kc, for which can be calculated as a function of Er and are seen to reduce by about one third over the Er range from 0.05 eV up to 0.5 eV. The rate coefficients, k, and product ion distributions for the NO+ and O2+ reactions with M had to be obtained experimentally relative to the calculated kc for the H3O+ reactions. The product ions of the NO+/ketones reactions initially proceed via the formation of excited (NO+M)* adduct ions that partially fragment, and the k reduces with Er as much as four times for the acetone reactions but remains close to their respective kc for the higher-order ketones indicating long lifetimes of the (NO+M)* ions with respect to the stabilising collision times with He atoms. The k for the O2+/ketones dissociative charge transfer reactions are observed to be greater than their calculated kc implying that long distance electron transfer occurs.n

Název v anglickém jazyce

Ion chemistry at elevated ion–molecule interaction energies in a selected ion flow-drift tube: reactions of H3O+, NO+ and O2+ with saturated aliphatic ketones

Popis výsledku anglicky

The reactions of H3O+, NO+ and O2+ ions with a homologous series of six aliphatic ketones, viz. acetone through 2-octanone, have been investigated in a helium-buffered selected ion flow-drift tube, SIFDT, in order to reveal their dependencies on ion–molecule interaction energies, Er, and to gain insight into their mechanisms. The ultimate motivation is to allow analysis and absolute quantification of trace amounts of ketones and other volatile organic compounds in air using selected ion flow-drift tube mass spectrometry, SIFDT-MS. The reactions of H3O+ with the ketone molecules, M, proceed via exothermic proton transfer producing MH+ ions, the collisional rate coefficients, kc, for which can be calculated as a function of Er and are seen to reduce by about one third over the Er range from 0.05 eV up to 0.5 eV. The rate coefficients, k, and product ion distributions for the NO+ and O2+ reactions with M had to be obtained experimentally relative to the calculated kc for the H3O+ reactions. The product ions of the NO+/ketones reactions initially proceed via the formation of excited (NO+M)* adduct ions that partially fragment, and the k reduces with Er as much as four times for the acetone reactions but remains close to their respective kc for the higher-order ketones indicating long lifetimes of the (NO+M)* ions with respect to the stabilising collision times with He atoms. The k for the O2+/ketones dissociative charge transfer reactions are observed to be greater than their calculated kc implying that long distance electron transfer occurs.n

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/GJ17-13157Y" target="_blank" >GJ17-13157Y: Metody hmotnostní spektrometrie založené na iontové chemii pro rychlé stanovení biogenních těkavých organických látek vedoucích k znečištění atmosféry</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Physical Chemistry Chemical Physics

ISSN

1463-9076

e-ISSN

—

Svazek periodika

19

Číslo periodika v rámci svazku

47

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

10

Strana od-do

31714-31723

Kód UT WoS článku

000417295800021

EID výsledku v databázi Scopus

2-s2.0-85038352492