Electrochemical monitoring of the co-extraction of water with hydrated ions into an organic solvent

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00486652" target="_blank" >RIV/61388955:_____/18:00486652 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.elecom.2018.01.017" target="_blank" >http://dx.doi.org/10.1016/j.elecom.2018.01.017</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.elecom.2018.01.017" target="_blank" >10.1016/j.elecom.2018.01.017</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Electrochemical monitoring of the co-extraction of water with hydrated ions into an organic solvent

Popis výsledku v původním jazyce

An electrochemical cell based on the interface between two immiscible electrolyte solutions (ITIES) was designed and used to study the co-extraction of water with hydrated chloride ions from the aqueous to the organic solvent phase. The interfacial potential was controlled by the distribution of a common tetralkylammonium (TAA+) ion. Transfer of hydrated chloride ions is accompanied by the transfer of TAA+, decreasing its concentration on the aqueous side of the interface. Changes in the TAA+ concentration at the interface were monitored by measuring the open circuit potential (OCP). The proposed mechanism of TAACl transport involves a follow-up reaction with the co-extracted water molecules, leading to the formation of clusters of water containing TAACl in the organic phase.

Název v anglickém jazyce

Electrochemical monitoring of the co-extraction of water with hydrated ions into an organic solvent

Popis výsledku anglicky

An electrochemical cell based on the interface between two immiscible electrolyte solutions (ITIES) was designed and used to study the co-extraction of water with hydrated chloride ions from the aqueous to the organic solvent phase. The interfacial potential was controlled by the distribution of a common tetralkylammonium (TAA+) ion. Transfer of hydrated chloride ions is accompanied by the transfer of TAA+, decreasing its concentration on the aqueous side of the interface. Changes in the TAA+ concentration at the interface were monitored by measuring the open circuit potential (OCP). The proposed mechanism of TAACl transport involves a follow-up reaction with the co-extracted water molecules, leading to the formation of clusters of water containing TAACl in the organic phase.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

<a href="/cs/project/GA17-09980S" target="_blank" >GA17-09980S: Biomimetická elektrochemie emulzních mikrokapek na polarizovaném rozhraní dvou nemísitelných roztoků elektrolytů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2018

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Electrochemistry Communications

ISSN

1388-2481

e-ISSN

—

Svazek periodika

88

Číslo periodika v rámci svazku

MAR 2018

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

4

Strana od-do

57-60

Kód UT WoS článku

000426512900013

EID výsledku v databázi Scopus

2-s2.0-85041483665