Electrochemical, EPR, and computational study of pyrene conjugates-precursors for novel type of organic semiconductors

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F22%3A00549368" target="_blank" >RIV/61388955:_____/22:00549368 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22310/22:43925671

Výsledek na webu

<a href="http://hdl.handle.net/11104/0325381" target="_blank" >http://hdl.handle.net/11104/0325381</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10008-021-05094-7" target="_blank" >10.1007/s10008-021-05094-7</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Electrochemical, EPR, and computational study of pyrene conjugates-precursors for novel type of organic semiconductors

Popis výsledku v původním jazyce

A series of nine precursors for pyrene-based biodegradable organic (semi)conductors having tetrasubstituted double bond as a central organic core and photo- or redox active centers attached at this core were investigated electrochemically in aprotic media at various electrodes. The influence of individual parts of the molecule on the redox properties were determined, the radical intermediates were intercepted using in situ EPR spectroelectrochemical experiments, the respective mechanisms were discussed, the difference between the first oxidation and the first reduction potential, respectively, were determined, and the experimental data were correlated with quantum chemical calculations.

Název v anglickém jazyce

Electrochemical, EPR, and computational study of pyrene conjugates-precursors for novel type of organic semiconductors

Popis výsledku anglicky

A series of nine precursors for pyrene-based biodegradable organic (semi)conductors having tetrasubstituted double bond as a central organic core and photo- or redox active centers attached at this core were investigated electrochemically in aprotic media at various electrodes. The influence of individual parts of the molecule on the redox properties were determined, the radical intermediates were intercepted using in situ EPR spectroelectrochemical experiments, the respective mechanisms were discussed, the difference between the first oxidation and the first reduction potential, respectively, were determined, and the experimental data were correlated with quantum chemical calculations.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

<a href="/cs/project/GA18-12150S" target="_blank" >GA18-12150S: Syntéza a charakterizace polovodivých supramolekul nového typu a jejich použití pro přípravu organických tranzistorů (OFET)</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Solid State Electrochemistry

ISSN

1432-8488

e-ISSN

1433-0768

Svazek periodika

26

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

12

Strana od-do

503-514

Kód UT WoS článku

000725466100001

EID výsledku v databázi Scopus

2-s2.0-85120443548