Rapid and straightforward electrochemical approach for the determination of the toxic food azo dye tartrazine using sensors based on silver solid amalgam

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F23%3A00568891" target="_blank" >RIV/61388955:_____/23:00568891 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11310/23:10472870

Výsledek na webu

<a href="https://hdl.handle.net/11104/0340170" target="_blank" >https://hdl.handle.net/11104/0340170</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jelechem.2023.117250" target="_blank" >10.1016/j.jelechem.2023.117250</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Rapid and straightforward electrochemical approach for the determination of the toxic food azo dye tartrazine using sensors based on silver solid amalgam

Popis výsledku v původním jazyce

The research paper reports for the first time the investigation of the electrochemical reduction of the synthetic food azo dye tartrazine (TZ) on three different types of silver solid amalgam electrodes (AgSAEs), in particular, the polished one (p-AgSAE), covered by mercury film (f-AgSAE) or by mercury meniscus (m-AgSAE), and the comparison with dropping mercury electrode. The highest reduction peak of TZ on AgSEAs was obtained in the Britton-Robinson buffer (pH 3.4). It was shown that the accumulation step can considerably increase the peak height of TZ reduction. Two adsorptive stripping voltammetric techniques, the linear sweep (LS-AdSV) and the differential pulse (DP-AdSV), were used to develop the simple, rapid, and sensitive methods for the determination of TZ based on its reduction on the working AgSAE. The results showed that all three AgSAEs can be applied for electroanalysis of TZ, however, the best limit of detection (0.078 μmol L−1) and the limit of quantification (0.24 μmol L−1) were obtained for m-AgSAE using LS-AdSV. The developed procedures were successfully applied for TZ determination in soft drink, succade, and veterinary drug using a standard addition method. Therefore, the AgSAEs have been demonstrated to be beneficial electrochemical tools for food products’ quality and safety monitoring.

Název v anglickém jazyce

Rapid and straightforward electrochemical approach for the determination of the toxic food azo dye tartrazine using sensors based on silver solid amalgam

Popis výsledku anglicky

The research paper reports for the first time the investigation of the electrochemical reduction of the synthetic food azo dye tartrazine (TZ) on three different types of silver solid amalgam electrodes (AgSAEs), in particular, the polished one (p-AgSAE), covered by mercury film (f-AgSAE) or by mercury meniscus (m-AgSAE), and the comparison with dropping mercury electrode. The highest reduction peak of TZ on AgSEAs was obtained in the Britton-Robinson buffer (pH 3.4). It was shown that the accumulation step can considerably increase the peak height of TZ reduction. Two adsorptive stripping voltammetric techniques, the linear sweep (LS-AdSV) and the differential pulse (DP-AdSV), were used to develop the simple, rapid, and sensitive methods for the determination of TZ based on its reduction on the working AgSAE. The results showed that all three AgSAEs can be applied for electroanalysis of TZ, however, the best limit of detection (0.078 μmol L−1) and the limit of quantification (0.24 μmol L−1) were obtained for m-AgSAE using LS-AdSV. The developed procedures were successfully applied for TZ determination in soft drink, succade, and veterinary drug using a standard addition method. Therefore, the AgSAEs have been demonstrated to be beneficial electrochemical tools for food products’ quality and safety monitoring.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

<a href="/cs/project/GA20-01589S" target="_blank" >GA20-01589S: Nové strategie pro zlepšení senzorových vlastností nových elektrodových materiálů prostřednictvím jejich předúpravy či modifikace povrchu</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Electroanalytical Chemistry

ISSN

1572-6657

e-ISSN

1873-2569

Svazek periodika

932

Číslo periodika v rámci svazku

MAR 2023

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

9

Strana od-do

117250

Kód UT WoS článku

000939878900001

EID výsledku v databázi Scopus

2-s2.0-85150790794