Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F17%3A00486998" target="_blank" >RIV/61388963:_____/17:00486998 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1007/s11224-016-0854-2" target="_blank" >http://dx.doi.org/10.1007/s11224-016-0854-2</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11224-016-0854-2" target="_blank" >10.1007/s11224-016-0854-2</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group

Popis výsledku v původním jazyce

Nine pentafluorosulfuranyl (SF5)-containing aromatic compounds have been characterized crystallographically. The SF5 group has an umbrella geometry, and the sulfur atom in the SF5 group is in an approximately octahedral coordination environment. All S-F bond lengths [1.572(3)-1.618(3) ] are very similar, and the C-S-F-ax bond angles [178.94(14)-180A degrees] are very close to each other. The angle of two adjacent F-eq is approximately 90A degrees. The intramolecular and intermolecular interactions such as C-aryl-H center dot center dot center dot F-eq, C-aryl-H center dot center dot center dot O/N/F/Cl interactions, and pi-stacking interactions play a very important role in their three-dimensional packing frameworks.

Název v anglickém jazyce

Single crystal X-ray structural features of aromatic compounds having a pentafluorosulfuranyl (SF5) functional group

Popis výsledku anglicky

Nine pentafluorosulfuranyl (SF5)-containing aromatic compounds have been characterized crystallographically. The SF5 group has an umbrella geometry, and the sulfur atom in the SF5 group is in an approximately octahedral coordination environment. All S-F bond lengths [1.572(3)-1.618(3) ] are very similar, and the C-S-F-ax bond angles [178.94(14)-180A degrees] are very close to each other. The angle of two adjacent F-eq is approximately 90A degrees. The intramolecular and intermolecular interactions such as C-aryl-H center dot center dot center dot F-eq, C-aryl-H center dot center dot center dot O/N/F/Cl interactions, and pi-stacking interactions play a very important role in their three-dimensional packing frameworks.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Structural Chemistry

ISSN

1040-0400

e-ISSN

—

Svazek periodika

28

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

11

Strana od-do

723-733

Kód UT WoS článku

000400574100018

EID výsledku v databázi Scopus

2-s2.0-84990856298