Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F24%3A00598277" target="_blank" >RIV/61388963:_____/24:00598277 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216305:26310/24:PU152146

Výsledek na webu

<a href="https://doi.org/10.1021/acsomega.4c04616" target="_blank" >https://doi.org/10.1021/acsomega.4c04616</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsomega.4c04616" target="_blank" >10.1021/acsomega.4c04616</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

Popis výsledku v původním jazyce

The anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole.

Název v anglickém jazyce

Epitaxial Guidance of Adamantyl-Substituted Polythiophenes by Self-Assembled Monolayers

Popis výsledku anglicky

The anisotropic nature of charge transport through organic materials requires high control over the self-assembly of the organic materials. This is particularly so for conductive polymers, where transport occurs mainly along the polymers' backbone. Herein, we demonstrate the use of self-assembled monolayers (SAMs) to influence the self-assembly of poly(3-adamantylmethylthiophene). We employ two different SAMs, which interact with either the adamantyl- or the thiophene-functionality, respectively, and acquire distinct topologies as compared to the unmodified Au(111) surface. We compare these results with unmodified glass and mica (muscovite) surfaces, which are typically employed in the field of optoelectronics. We prove the usefulness and applicability of epitaxial effects and adamantyl substituents for organic electronics. This presents a viable way toward improved electronic performance for the field as a whole.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

<a href="/cs/project/8J24AT022" target="_blank" >8J24AT022: Inženýrství bočního řetězce adamantanu pro vysoce uspořádané organické polovodivé pigmenty a barviva</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Omega

ISSN

2470-1343

e-ISSN

2470-1343

Svazek periodika

9

Číslo periodika v rámci svazku

37

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

38733-38742

Kód UT WoS článku

001305360700001

EID výsledku v databázi Scopus

2-s2.0-85202983590