Anionic tert-butyl-calix[4]arenes substituted at the narrow and wide rim by cobalt bis(dicarbollide)(1-) ions and CMPO-groups. Effect of stereochemistry and ratios of the functional groups on the platform on the extraction efficiency for Ln(III)/An(III)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F13%3A00397812" target="_blank" >RIV/61388980:_____/13:00397812 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.04.035" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2013.04.035</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.04.035" target="_blank" >10.1016/j.jorganchem.2013.04.035</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Anionic tert-butyl-calix[4]arenes substituted at the narrow and wide rim by cobalt bis(dicarbollide)(1-) ions and CMPO-groups. Effect of stereochemistry and ratios of the functional groups on the platform on the extraction efficiency for Ln(III)/An(III)

Popis výsledku v původním jazyce

Two ionic calix[4]arenes substituted at the narrow rim with an unpaired number (n) of cobalt bis(dicarbollide)(1-) anions (1-) (n = 1 and 3) and (4 - n) CMPO groups (3c, 4c) have been synthesized via a three-step procedure based on nitrile substituted calix[4]arene precursors. Conjointly with them, the compound with a paired ratio of the groups, where n = 2 and the same substituents are located in mutually adjacent 1,2-positions, is reported (5c). Another compound with the paired ratio, but from a widerim series (6c) (n = 2) was successfully prepared starting from calix[4]arenes substituted with two nitro functions and two -OH sites available for further modifications. The reaction steps included, a) O-alkylation of the hydroxy functions present on the same rim by the 1-dioxane derivative [8-O(CH2CH2)2O(+)-1,2-C2B9H10)-(1,2-C2B9H11)-3,3-Co] (2) used as the reactive building block resulting in the respective ionic nitriles (3a-5a) or nitro compound (6a); b) Reduction of the nitrile or

Název v anglickém jazyce

Anionic tert-butyl-calix[4]arenes substituted at the narrow and wide rim by cobalt bis(dicarbollide)(1-) ions and CMPO-groups. Effect of stereochemistry and ratios of the functional groups on the platform on the extraction efficiency for Ln(III)/An(III)

Popis výsledku anglicky

Two ionic calix[4]arenes substituted at the narrow rim with an unpaired number (n) of cobalt bis(dicarbollide)(1-) anions (1-) (n = 1 and 3) and (4 - n) CMPO groups (3c, 4c) have been synthesized via a three-step procedure based on nitrile substituted calix[4]arene precursors. Conjointly with them, the compound with a paired ratio of the groups, where n = 2 and the same substituents are located in mutually adjacent 1,2-positions, is reported (5c). Another compound with the paired ratio, but from a widerim series (6c) (n = 2) was successfully prepared starting from calix[4]arenes substituted with two nitro functions and two -OH sites available for further modifications. The reaction steps included, a) O-alkylation of the hydroxy functions present on the same rim by the 1-dioxane derivative [8-O(CH2CH2)2O(+)-1,2-C2B9H10)-(1,2-C2B9H11)-3,3-Co] (2) used as the reactive building block resulting in the respective ionic nitriles (3a-5a) or nitro compound (6a); b) Reduction of the nitrile or

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CA - Anorganická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA104%2F09%2F0668" target="_blank" >GA104/09/0668: Vývoj a optimalizace extrakčních činidel pro radionuklidy založených na borových klastrových aniontech</a><br>

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

—

Svazek periodika

747

Číslo periodika v rámci svazku

december

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

12

Strana od-do

155-166

Kód UT WoS článku

000326116500022

EID výsledku v databázi Scopus

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