Novel complexes of Co2+, Ni2+, and Cu2+ with N-(phosphonomethyl)aminosuccinic acid
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F14%3A00392657" target="_blank" >RIV/61388980:_____/14:00392657 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1007/s10973-013-3191-3" target="_blank" >http://dx.doi.org/10.1007/s10973-013-3191-3</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10973-013-3191-3" target="_blank" >10.1007/s10973-013-3191-3</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Novel complexes of Co2+, Ni2+, and Cu2+ with N-(phosphonomethyl)aminosuccinic acid
Popis výsledku v původním jazyce
Complexes of Co2?, Ni2 ?, and Cu2? with N-(phosphonomethyl)aminosuccinic acid (H4PMAS) of general formula Na2MPMAS nH2O [M=Co(II), Ni(II), Cu(II), n?number of water molecules] were synthesized. Based on interpretation of diffusion reflectance spectroscopy, structure of all complexes is based on distorted octahedral. Analysis of IR spectra of Co(II), Ni(II), and Cu(II) N-(phosphonomethyl)aminosuccinates demonstrated that metal ions are coordinated to the ligand through nitrogen atom of the imino group, oxygen atoms of the aand b-carboxyl groups as well as oxygen atom of the phosphonic group of the H4PMAS. We demonstrated that thermal stability of complexes increases in sequence Cu(II)/Ni(II)/Co(II), obviously as a result of change over from the dimericto polymeric character of the initial complex. Complete decomposition of ligand occurs at these temperatures and is accompanied by release of H2O, CO2, and NO2. The final products of thermal decomposition of the complexes are mixtures of
Název v anglickém jazyce
Novel complexes of Co2+, Ni2+, and Cu2+ with N-(phosphonomethyl)aminosuccinic acid
Popis výsledku anglicky
Complexes of Co2?, Ni2 ?, and Cu2? with N-(phosphonomethyl)aminosuccinic acid (H4PMAS) of general formula Na2MPMAS nH2O [M=Co(II), Ni(II), Cu(II), n?number of water molecules] were synthesized. Based on interpretation of diffusion reflectance spectroscopy, structure of all complexes is based on distorted octahedral. Analysis of IR spectra of Co(II), Ni(II), and Cu(II) N-(phosphonomethyl)aminosuccinates demonstrated that metal ions are coordinated to the ligand through nitrogen atom of the imino group, oxygen atoms of the aand b-carboxyl groups as well as oxygen atom of the phosphonic group of the H4PMAS. We demonstrated that thermal stability of complexes increases in sequence Cu(II)/Ni(II)/Co(II), obviously as a result of change over from the dimericto polymeric character of the initial complex. Complete decomposition of ligand occurs at these temperatures and is accompanied by release of H2O, CO2, and NO2. The final products of thermal decomposition of the complexes are mixtures of
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CA - Anorganická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2014
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Thermal Analysis and Calorimetry
ISSN
1388-6150
e-ISSN
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Svazek periodika
115
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
HU - Maďarsko
Počet stran výsledku
10
Strana od-do
697-706
Kód UT WoS článku
000329621100084
EID výsledku v databázi Scopus
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