Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10]2− anion via soft-route

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F20%3A00521907" target="_blank" >RIV/61388980:_____/20:00521907 - isvavai.cz</a>

Výsledek na webu

<a href="http://hdl.handle.net/11104/0306453" target="_blank" >http://hdl.handle.net/11104/0306453</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2020.121132" target="_blank" >10.1016/j.jorganchem.2020.121132</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10]2− anion via soft-route

Popis výsledku v původním jazyce

Series of closo-decaborate (NH4)2[B10H10] derivatives were prepared by their direct reaction with ligand L (alcohols or nitriles) via an auto-catalyzed reaction with NH4+ present as a counter cation. The reactions were carried out under mild conditions in open air at reflux in the absence of any subsidiary catalyst. The yield and degree of substitution of the derivatives depend on the duration of the reaction and the applied temperature. Derivatives were characterized by NMR, MS-ESI and TLC. The study elaborates the proposed mechanism of the nucleophilic substitution on [B10H10]2– by illustrating the assistance of an initiator to catalyze the reaction.

Název v anglickém jazyce

Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10]2− anion via soft-route

Popis výsledku anglicky

Series of closo-decaborate (NH4)2[B10H10] derivatives were prepared by their direct reaction with ligand L (alcohols or nitriles) via an auto-catalyzed reaction with NH4+ present as a counter cation. The reactions were carried out under mild conditions in open air at reflux in the absence of any subsidiary catalyst. The yield and degree of substitution of the derivatives depend on the duration of the reaction and the applied temperature. Derivatives were characterized by NMR, MS-ESI and TLC. The study elaborates the proposed mechanism of the nucleophilic substitution on [B10H10]2– by illustrating the assistance of an initiator to catalyze the reaction.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

—

Svazek periodika

910

Číslo periodika v rámci svazku

MAR

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

6

Strana od-do

121132

Kód UT WoS článku

000514191300003

EID výsledku v databázi Scopus

2-s2.0-85078656375