Supramolecular self-assembly of novel thermo-responsive double-hydrophilic and hydrophobic Y-shaped [MPEO-b-PEtOx-b-(PCL)2] terpolymers

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00446010" target="_blank" >RIV/61389013:_____/15:00446010 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1039/C5RA08298F" target="_blank" >http://dx.doi.org/10.1039/C5RA08298F</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C5RA08298F" target="_blank" >10.1039/C5RA08298F</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Supramolecular self-assembly of novel thermo-responsive double-hydrophilic and hydrophobic Y-shaped [MPEO-b-PEtOx-b-(PCL)2] terpolymers

Popis výsledku v původním jazyce

Nonlinear amphiphilic block copolymer architectures with precisely controlled structures bring new challenges to biomedical materials research. The paper describes the straightforward synthesis of new ?snake tongue? Y-shaped terpolymers containing poly(ethylene oxide) (PEO), poly(2-ethyl-2-oxazoline) (PEtOx) and poly(?-caprolactone) (PCL) blocks into structure [AB(C)2] (herein referred to as [MPEO44-b-PEtOx252-b-(PCL)244], [MPEO44-b-PEtOx252-b-(PCL)287], [MPEO44-b-PEtOx252-b-(PCL)2131]). A series of well-defined Y-shaped terpolymers were successfully synthesised by a combination of living cationic and anionic ring-opening polymerization (ROP). The selected Y-shaped [MPEO44-b-PEtOx252-b-(PCL)244] terpolymer self-assembly was characterised in detail by static and dynamic light scattering, nanoparticle tracking analysis and cryo-transmission electron microscopy. The physico-chemical properties as well as the molecular architecture effect on the self-assembled structures and on the LCST we

Název v anglickém jazyce

Supramolecular self-assembly of novel thermo-responsive double-hydrophilic and hydrophobic Y-shaped [MPEO-b-PEtOx-b-(PCL)2] terpolymers

Popis výsledku anglicky

Nonlinear amphiphilic block copolymer architectures with precisely controlled structures bring new challenges to biomedical materials research. The paper describes the straightforward synthesis of new ?snake tongue? Y-shaped terpolymers containing poly(ethylene oxide) (PEO), poly(2-ethyl-2-oxazoline) (PEtOx) and poly(?-caprolactone) (PCL) blocks into structure [AB(C)2] (herein referred to as [MPEO44-b-PEtOx252-b-(PCL)244], [MPEO44-b-PEtOx252-b-(PCL)287], [MPEO44-b-PEtOx252-b-(PCL)2131]). A series of well-defined Y-shaped terpolymers were successfully synthesised by a combination of living cationic and anionic ring-opening polymerization (ROP). The selected Y-shaped [MPEO44-b-PEtOx252-b-(PCL)244] terpolymer self-assembly was characterised in detail by static and dynamic light scattering, nanoparticle tracking analysis and cryo-transmission electron microscopy. The physico-chemical properties as well as the molecular architecture effect on the self-assembled structures and on the LCST we

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CD - Makromolekulární chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2015

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

RSC Advances

ISSN

2046-2069

e-ISSN

—

Svazek periodika

5

Číslo periodika v rámci svazku

77

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

11

Strana od-do

62844-62854

Kód UT WoS článku

000358620100063

EID výsledku v databázi Scopus

2-s2.0-84938223470